"Living" radical polymerization of butyl methacrylate by a reverse atrp process

Wenjun Wang; Yuping Dong; Qianshu Li

"Living" radical polymerization of butyl methacrylate by a reverse atrp process

Wenjun Wang, Yuping Dong, Qianshu Li

School of Material Science and Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

A new eflccient catalyst system(FeCl ₃/2PPh ₃) for the "living"/controlled radical polymerization of butyl methacrylate by a reverse ATRP process was reported in this paper. With the presence of this catalyst system, the number-average molecular weights of the obtained polymer increased in direct proportion with monomer conversion, and the MWDs (molecular weight disctributions) were narrow throughout the reactions(1.17 < M̄ _w/M̄ _n < 1.22). This reaction system did not include the conventional initiators which were used to generate the primary radicals.

Original language	English
Pages (from-to)	795
Number of pages	1
Journal	Acta Polymerica Sinica
Issue number	6
Publication status	Published - 2001

Keywords

"Living" radical polymerization
Butyl methacrylate
Reverse ATRP

Cite this

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AU - Wang, Wenjun

AU - Dong, Yuping

AU - Li, Qianshu

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AB - A new eflccient catalyst system(FeCl 3/2PPh 3) for the "living"/controlled radical polymerization of butyl methacrylate by a reverse ATRP process was reported in this paper. With the presence of this catalyst system, the number-average molecular weights of the obtained polymer increased in direct proportion with monomer conversion, and the MWDs (molecular weight disctributions) were narrow throughout the reactions(1.17 < M̄ w/M̄ n < 1.22). This reaction system did not include the conventional initiators which were used to generate the primary radicals.

KW - "Living" radical polymerization

KW - Butyl methacrylate

KW - Reverse ATRP

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JO - Acta Polymerica Sinica

JF - Acta Polymerica Sinica

IS - 6

ER -

"Living" radical polymerization of butyl methacrylate by a reverse atrp process

Abstract

Keywords

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