Inhibiting gas generation to achieve ultralong-lifespan lithium-ion batteries at low temperatures

Zeheng Li, Nan Yao, Legeng Yu, Yu Xing Yao, Cheng Bin Jin, Yi Yang, Ye Xiao, Xin Yang Yue, Wen Long Cai, Lei Xu, Peng Wu, Chong Yan*, Qiang Zhang*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

32 Citations (Scopus)

Abstract

The notorious low-temperature sensitivity of contemporary lithium-ion batteries (LIBs) has long restricted their low-temperature applications. Introduction of high-content low-freezing-point solvents significantly expands the low-temperature operation border of LIBs. However, they react violently with metallic lithium (Li) plated at low temperatures (−20°C or lower), resulting in severe gas generation and a limited lifespan. We reveal the mechanism of gas generation and develop a high-concentration ethyl acetate (EA)-based electrolyte. The dense and uniform solid electrolyte interphase formed by the joint decomposition of rich anions and additive effectively passivate the plated Li at low temperatures. The proposed electrolyte enables the LiNi0.8Co0.1Mn0.1O2 (NCM811)/graphite pouch cell to be stably cycled at −20°C and 0.2 C for a record-breaking lifetime of more than 1 year (1,400 cycles). The NCM811/graphite pouch cell exhibits good fast-charging capability (0.5 C) at −20°C with a capacity decay rate as low as 0.0097% per cycle during 4,000 cycles.

Original languageEnglish
Pages (from-to)2274-2292
Number of pages19
JournalMatter
Volume6
Issue number7
DOIs
Publication statusPublished - 5 Jul 2023

Keywords

  • MAP4: Demonstrate
  • gas generation inhibition
  • high-concentration electrolyte
  • lithium plating
  • lithium-ion batteries
  • low temperatures

Fingerprint

Dive into the research topics of 'Inhibiting gas generation to achieve ultralong-lifespan lithium-ion batteries at low temperatures'. Together they form a unique fingerprint.

Cite this