Hydroxo-Lanthanide Cluster Organic Framework Built by Hexanuclear Cluster Units

Wei Hui Fang; Guo Yu Yang

doi:10.1007/s10876-014-0717-1

Hydroxo-Lanthanide Cluster Organic Framework Built by Hexanuclear Cluster Units

Wei Hui Fang, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

A novel hydroxo-lanthanide cluster organic framework, Sm₃L₈(μ₃-OH)(H₂O)·H₂O (1), derived from the 4-pyridin-4-ylbenzoic acid (HL) has been hydrothermally made and structurally characterized by single crystal X-ray diffraction. Structure analysis shows the hexanuclear Sm₆ cluster unit is composed of inorganic tetranuclear hydroxo [Sm₄(OH)₂]¹⁰⁺ (Sm₄) cluster and dimeric [Sm₂(COO)₄]²⁺ (Sm₂) core. The Sm₆ cluster units are connected by L ligands to form a 2D Ln-based cluster organic framework. From the topological point of view, the layer architecture can be described as 4-connected sql net. Furthermore, the elemental analysis, PXRD, IR and TGA are also studied.

Original language	English
Pages (from-to)	1401-1411
Number of pages	11
Journal	Journal of Cluster Science
Volume	25
Issue number	5
DOIs	https://doi.org/10.1007/s10876-014-0717-1
Publication status	Published - 1 Sept 2014
Externally published	Yes

Keywords

Hexanuclear
Hydrothermal synthesis
Lanthanide cluster
Sql

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10.1007/s10876-014-0717-1

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title = "Hydroxo-Lanthanide Cluster Organic Framework Built by Hexanuclear Cluster Units",

abstract = "A novel hydroxo-lanthanide cluster organic framework, Sm3L8(μ3-OH)(H2O)·H2O (1), derived from the 4-pyridin-4-ylbenzoic acid (HL) has been hydrothermally made and structurally characterized by single crystal X-ray diffraction. Structure analysis shows the hexanuclear Sm6 cluster unit is composed of inorganic tetranuclear hydroxo [Sm4(OH)2]10+ (Sm4) cluster and dimeric [Sm2(COO)4]2+ (Sm2) core. The Sm6 cluster units are connected by L ligands to form a 2D Ln-based cluster organic framework. From the topological point of view, the layer architecture can be described as 4-connected sql net. Furthermore, the elemental analysis, PXRD, IR and TGA are also studied.",

keywords = "Hexanuclear, Hydrothermal synthesis, Lanthanide cluster, Sql",

author = "Fang, {Wei Hui} and Yang, {Guo Yu}",

note = "Publisher Copyright: {\textcopyright} 2014, Springer Science+Business Media New York.",

year = "2014",

month = sep,

day = "1",

doi = "10.1007/s10876-014-0717-1",

language = "English",

volume = "25",

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journal = "Journal of Cluster Science",

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T1 - Hydroxo-Lanthanide Cluster Organic Framework Built by Hexanuclear Cluster Units

AU - Fang, Wei Hui

AU - Yang, Guo Yu

PY - 2014/9/1

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N2 - A novel hydroxo-lanthanide cluster organic framework, Sm3L8(μ3-OH)(H2O)·H2O (1), derived from the 4-pyridin-4-ylbenzoic acid (HL) has been hydrothermally made and structurally characterized by single crystal X-ray diffraction. Structure analysis shows the hexanuclear Sm6 cluster unit is composed of inorganic tetranuclear hydroxo [Sm4(OH)2]10+ (Sm4) cluster and dimeric [Sm2(COO)4]2+ (Sm2) core. The Sm6 cluster units are connected by L ligands to form a 2D Ln-based cluster organic framework. From the topological point of view, the layer architecture can be described as 4-connected sql net. Furthermore, the elemental analysis, PXRD, IR and TGA are also studied.

AB - A novel hydroxo-lanthanide cluster organic framework, Sm3L8(μ3-OH)(H2O)·H2O (1), derived from the 4-pyridin-4-ylbenzoic acid (HL) has been hydrothermally made and structurally characterized by single crystal X-ray diffraction. Structure analysis shows the hexanuclear Sm6 cluster unit is composed of inorganic tetranuclear hydroxo [Sm4(OH)2]10+ (Sm4) cluster and dimeric [Sm2(COO)4]2+ (Sm2) core. The Sm6 cluster units are connected by L ligands to form a 2D Ln-based cluster organic framework. From the topological point of view, the layer architecture can be described as 4-connected sql net. Furthermore, the elemental analysis, PXRD, IR and TGA are also studied.

KW - Hexanuclear

KW - Hydrothermal synthesis

KW - Lanthanide cluster

KW - Sql

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JO - Journal of Cluster Science

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Hydroxo-Lanthanide Cluster Organic Framework Built by Hexanuclear Cluster Units

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Keywords

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