Hydrothermal synthesis and crystal structure of a novel 1-D chain structure constructed from polyoxometalates and coordination complex fragments

Xiao Bing Cui; Ji Qing Xu; Ying Hua Sun; Yong Li; Ling Ye; Guo Yu Yang

doi:10.1016/j.inoche.2003.10.004

Hydrothermal synthesis and crystal structure of a novel 1-D chain structure constructed from polyoxometalates and coordination complex fragments

Xiao Bing Cui, Ji Qing Xu^*, Ying Hua Sun, Yong Li, Ling Ye, Guo Yu Yang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

The compound [Cu(en)₂]1.5[H₃As₆V ₁₅O₄₂(H₂O)] · 3H₂O 1 (en = ethylenediamine) has been synthesized and characterized by elemental analysis, IR spectrum and single crystal X-ray diffraction analysis. Crystal structure analysis reveals that compound 1 is not only the first example of one-dimensional sinusoidal chain structure constructed from polyoxometalates and coordination complex fragments but also the first example of one-dimensional chain of polyoxometalates where clusters are connected by one coordination complex fragment and two coordination complex fragments alternatively.

Original language	English
Pages (from-to)	58-61
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	7
Issue number	1
DOIs	https://doi.org/10.1016/j.inoche.2003.10.004
Publication status	Published - Jan 2004
Externally published	Yes

Keywords

Arsenic-vanadium cluster
Crystal structure
Hydrothermal synthesis
One-dimensional chain
Polyoxometalate

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10.1016/j.inoche.2003.10.004

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title = "Hydrothermal synthesis and crystal structure of a novel 1-D chain structure constructed from polyoxometalates and coordination complex fragments",

abstract = "The compound [Cu(en)2]1.5[H3As6V 15O42(H2O)] · 3H2O 1 (en = ethylenediamine) has been synthesized and characterized by elemental analysis, IR spectrum and single crystal X-ray diffraction analysis. Crystal structure analysis reveals that compound 1 is not only the first example of one-dimensional sinusoidal chain structure constructed from polyoxometalates and coordination complex fragments but also the first example of one-dimensional chain of polyoxometalates where clusters are connected by one coordination complex fragment and two coordination complex fragments alternatively.",

keywords = "Arsenic-vanadium cluster, Crystal structure, Hydrothermal synthesis, One-dimensional chain, Polyoxometalate",

author = "Cui, {Xiao Bing} and Xu, {Ji Qing} and Sun, {Ying Hua} and Yong Li and Ling Ye and Yang, {Guo Yu}",

year = "2004",

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doi = "10.1016/j.inoche.2003.10.004",

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T1 - Hydrothermal synthesis and crystal structure of a novel 1-D chain structure constructed from polyoxometalates and coordination complex fragments

AU - Cui, Xiao Bing

AU - Xu, Ji Qing

AU - Sun, Ying Hua

AU - Li, Yong

AU - Ye, Ling

AU - Yang, Guo Yu

PY - 2004/1

Y1 - 2004/1

N2 - The compound [Cu(en)2]1.5[H3As6V 15O42(H2O)] · 3H2O 1 (en = ethylenediamine) has been synthesized and characterized by elemental analysis, IR spectrum and single crystal X-ray diffraction analysis. Crystal structure analysis reveals that compound 1 is not only the first example of one-dimensional sinusoidal chain structure constructed from polyoxometalates and coordination complex fragments but also the first example of one-dimensional chain of polyoxometalates where clusters are connected by one coordination complex fragment and two coordination complex fragments alternatively.

AB - The compound [Cu(en)2]1.5[H3As6V 15O42(H2O)] · 3H2O 1 (en = ethylenediamine) has been synthesized and characterized by elemental analysis, IR spectrum and single crystal X-ray diffraction analysis. Crystal structure analysis reveals that compound 1 is not only the first example of one-dimensional sinusoidal chain structure constructed from polyoxometalates and coordination complex fragments but also the first example of one-dimensional chain of polyoxometalates where clusters are connected by one coordination complex fragment and two coordination complex fragments alternatively.

KW - Arsenic-vanadium cluster

KW - Crystal structure

KW - Hydrothermal synthesis

KW - One-dimensional chain

KW - Polyoxometalate

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DO - 10.1016/j.inoche.2003.10.004

M3 - Article

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SN - 1387-7003

VL - 7

SP - 58

EP - 61

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 1

ER -

Hydrothermal synthesis and crystal structure of a novel 1-D chain structure constructed from polyoxometalates and coordination complex fragments

Abstract

Keywords

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