Highly luminescent and stable lead-free cesium copper halide perovskite powders for UV-pumped phosphor-converted light-emitting diodes

Lingling Xie, Bingkun Chen, Fa Zhang, Ziheng Zhao, Xinxin Wang, Lijie Shi, Yue Liu, Lingling Huang, Ruibin Liu, Bingsuo Zou, Yongtian Wang

Research output: Contribution to journalArticlepeer-review

106 Citations (Scopus)

Abstract

Lead halide perovskites have drawn extensive attention over recent decades owing to their outstanding photoelectric performances. However, their toxicity and instability are big issues that need to be solved for further commercialization. Herein, we adopt a facile dry ball milling method to synthesize lead-free Cs3Cu2X5 (X = I, Cl) perovskites with photoluminescence (PL) quantum yield up to 60%. The optical features including broad emission spectrum, large Stokes shift, and long PL lifetime can be attributed to self-trapped exciton recombination. The as-synthesized blue emissive Cs3Cu2I5 and green emissive Cs3Cu2Cl5 lead-free perovskite powders have good thermal stability and photostability. Furthermore, UV-pumped phosphor-converted lightemitting diodes were obtained by using Cs3Cu2I5 and Cs3Cu2Cl5 as phosphors.

Original languageEnglish
Pages (from-to)768-775
Number of pages8
JournalPhotonics Research
Volume8
Issue number6
DOIs
Publication statusPublished - Jun 2020

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