Growth, Structure, and Properties of a Multifunctional Crystal Pr2CaB10O19

Jingcheng Feng; Youquan Liu; Yanling Cheng; Feidi Fan; Jun Shen; Zheshuai Lin; Heng Tu; Guochun Zhang

doi:10.1021/acs.inorgchem.1c01885

Growth, Structure, and Properties of a Multifunctional Crystal Pr₂CaB₁₀O₁₉

Jingcheng Feng, Youquan Liu, Yanling Cheng, Feidi Fan, Jun Shen, Zheshuai Lin, Heng Tu^*, Guochun Zhang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A new praseodymium-based borate crystal Pr2CaB10O19 (PCB) has been grown through the high temperature solution method. PCB crystallizes in monoclinic space group C2 with unit cell parameters of a = 10.9475(10) Å, b = 6.5343(7) Å, c = 9.0336(8) Å, β = 91.652(3)°, and Z = 2, in which B5O12 groups and PrO10 and CaO8 polyhedra constitute the three-dimensional framework. PCB exhibits a similar second harmonic response intensity to that of La2CaB10O19 and an intense orange fluorescence emission with a long fluorescence lifetime at about 610 nm excited by a xenon lamp light of 466 nm. The band gap, partial density of states, and birefringence have been investigated via theoretical calculations.

Original language	English
Pages (from-to)	10895-10898
Number of pages	4
Journal	Inorganic Chemistry
Volume	60
Issue number	15
DOIs	https://doi.org/10.1021/acs.inorgchem.1c01885
Publication status	Published - 2 Aug 2021
Externally published	Yes

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title = "Growth, Structure, and Properties of a Multifunctional Crystal Pr2CaB10O19",

abstract = "A new praseodymium-based borate crystal Pr2CaB10O19 (PCB) has been grown through the high temperature solution method. PCB crystallizes in monoclinic space group C2 with unit cell parameters of a = 10.9475(10) {\AA}, b = 6.5343(7) {\AA}, c = 9.0336(8) {\AA}, β = 91.652(3)°, and Z = 2, in which B5O12 groups and PrO10 and CaO8 polyhedra constitute the three-dimensional framework. PCB exhibits a similar second harmonic response intensity to that of La2CaB10O19 and an intense orange fluorescence emission with a long fluorescence lifetime at about 610 nm excited by a xenon lamp light of 466 nm. The band gap, partial density of states, and birefringence have been investigated via theoretical calculations.",

author = "Jingcheng Feng and Youquan Liu and Yanling Cheng and Feidi Fan and Jun Shen and Zheshuai Lin and Heng Tu and Guochun Zhang",

note = "Publisher Copyright: {\textcopyright} 2021 American Chemical Society.",

year = "2021",

month = aug,

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doi = "10.1021/acs.inorgchem.1c01885",

language = "English",

volume = "60",

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TY - JOUR

T1 - Growth, Structure, and Properties of a Multifunctional Crystal Pr2CaB10O19

AU - Feng, Jingcheng

AU - Liu, Youquan

AU - Cheng, Yanling

AU - Fan, Feidi

AU - Shen, Jun

AU - Lin, Zheshuai

AU - Tu, Heng

AU - Zhang, Guochun

PY - 2021/8/2

Y1 - 2021/8/2

N2 - A new praseodymium-based borate crystal Pr2CaB10O19 (PCB) has been grown through the high temperature solution method. PCB crystallizes in monoclinic space group C2 with unit cell parameters of a = 10.9475(10) Å, b = 6.5343(7) Å, c = 9.0336(8) Å, β = 91.652(3)°, and Z = 2, in which B5O12 groups and PrO10 and CaO8 polyhedra constitute the three-dimensional framework. PCB exhibits a similar second harmonic response intensity to that of La2CaB10O19 and an intense orange fluorescence emission with a long fluorescence lifetime at about 610 nm excited by a xenon lamp light of 466 nm. The band gap, partial density of states, and birefringence have been investigated via theoretical calculations.

AB - A new praseodymium-based borate crystal Pr2CaB10O19 (PCB) has been grown through the high temperature solution method. PCB crystallizes in monoclinic space group C2 with unit cell parameters of a = 10.9475(10) Å, b = 6.5343(7) Å, c = 9.0336(8) Å, β = 91.652(3)°, and Z = 2, in which B5O12 groups and PrO10 and CaO8 polyhedra constitute the three-dimensional framework. PCB exhibits a similar second harmonic response intensity to that of La2CaB10O19 and an intense orange fluorescence emission with a long fluorescence lifetime at about 610 nm excited by a xenon lamp light of 466 nm. The band gap, partial density of states, and birefringence have been investigated via theoretical calculations.

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DO - 10.1021/acs.inorgchem.1c01885

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SN - 0020-1669

VL - 60

SP - 10895

EP - 10898

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 15

ER -

Growth, Structure, and Properties of a Multifunctional Crystal Pr₂CaB₁₀O₁₉

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