Graphene-like carbon-nitrogen materials as anode materials for Li-ion and mg-ion batteries

Jianhang Zhang, Gang Liu*, Hechen Hu, Liyuan Wu, Qian Wang, Xiangjun Xin, Shanjun Li, Pengfei Lu

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

93 Citations (Scopus)

Abstract

Two-dimensional materials have been considered to be promising potential electrodes of metal-ion batteries. Here we explored the application of three graphene-like carbon-nitrogen structures as anode materials in lithium (Li)–ion and magnesium (Mg)-ion Batteries. We first studied the intrinsic characteristic of C2N, C3N, and g-C3N4, explored possible adsorption positions in each structure, studied the diffusion path, energy barrier, voltage profile, and theoretical capacity. Our results show that the theoretical capacities of C2N anode is 671.7 mAhg−1 for Li-ions and 588.4 mAhg−1 for Mg-ions, which makes it a promising anode material. C3N is not suitable as anode material. Because of the few absorptions sites, the capacity of g-C3N4 sheet is only 199.5 mAhg−1 for Li-ions and 319.2 mAhg−1for Mg-ions, which makes it unsuitable as anode material but its performance can be much improved when curled into nanotubes. Using Mg-ions instead of Li-ions can reduce the deformation of the material (for C2N) at the maximum concentration or improve the theoretical capacity (for C3N4), lowing the maximum open circuit voltage while improving the diffusion energy barrier.

Original languageEnglish
Pages (from-to)1026-1032
Number of pages7
JournalApplied Surface Science
Volume487
DOIs
Publication statusPublished - 1 Sept 2019
Externally publishedYes

Keywords

  • Anode material
  • Carbon-nitrogen anode material
  • Graphene-like material
  • Li-ion batteries
  • Mg-ion batteries
  • Nitrogen-doped graphene

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