FT-IR study on the curing reaction of isophorone diisocyanate with the glycidyl azide polymer and its prepolymer with nitrocellose

Yan Guang Wu; Yun Jun Luo; Zhen Ge; Lu Kui Zhao

FT-IR study on the curing reaction of isophorone diisocyanate with the glycidyl azide polymer and its prepolymer with nitrocellose

Yan Guang Wu, Yun Jun Luo^*, Zhen Ge, Lu Kui Zhao

^*Corresponding author for this work

School of Material Science and Engineering

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The glycidyl azide polymer (GAP)/isophorone diisocyanate (IPDI) system and GAP-IPDI/prepolymer/nitrocellose (NC) system were prepared. Their curing reaction kinetics was studied by FT-IR. The experimental results show that the reaction rates of the two systems increase with an increase in temperature. When the content of the curing catalyst T₁₂ is 0.025%, the apparent activation energy of the curing reaction for the two systems are 64.88 kJ/mol and 111.19 kJ/mol, respectively, and the reaction appeares as second-order kinetic reaction.

Original language	English
Pages (from-to)	43-46
Number of pages	4
Journal	Huozhayao Xuebao/Chinese Journal of Explosives and Propellants
Volume	36
Issue number	1
Publication status	Published - Feb 2013

Keywords

Curing reaction kinetics
FT-IR spectrum
Glycidyl azide polymer
IPDI
Isophorone diisocyanate
Nitrocellos
Physical chemistry

Cite this

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title = "FT-IR study on the curing reaction of isophorone diisocyanate with the glycidyl azide polymer and its prepolymer with nitrocellose",

abstract = "The glycidyl azide polymer (GAP)/isophorone diisocyanate (IPDI) system and GAP-IPDI/prepolymer/nitrocellose (NC) system were prepared. Their curing reaction kinetics was studied by FT-IR. The experimental results show that the reaction rates of the two systems increase with an increase in temperature. When the content of the curing catalyst T12 is 0.025%, the apparent activation energy of the curing reaction for the two systems are 64.88 kJ/mol and 111.19 kJ/mol, respectively, and the reaction appeares as second-order kinetic reaction.",

keywords = "Curing reaction kinetics, FT-IR spectrum, Glycidyl azide polymer, IPDI, Isophorone diisocyanate, Nitrocellos, Physical chemistry",

author = "Wu, {Yan Guang} and Luo, {Yun Jun} and Zhen Ge and Zhao, {Lu Kui}",

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journal = "Huozhayao Xuebao/Chinese Journal of Explosives and Propellants",

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TY - JOUR

T1 - FT-IR study on the curing reaction of isophorone diisocyanate with the glycidyl azide polymer and its prepolymer with nitrocellose

AU - Wu, Yan Guang

AU - Luo, Yun Jun

AU - Ge, Zhen

AU - Zhao, Lu Kui

PY - 2013/2

Y1 - 2013/2

N2 - The glycidyl azide polymer (GAP)/isophorone diisocyanate (IPDI) system and GAP-IPDI/prepolymer/nitrocellose (NC) system were prepared. Their curing reaction kinetics was studied by FT-IR. The experimental results show that the reaction rates of the two systems increase with an increase in temperature. When the content of the curing catalyst T12 is 0.025%, the apparent activation energy of the curing reaction for the two systems are 64.88 kJ/mol and 111.19 kJ/mol, respectively, and the reaction appeares as second-order kinetic reaction.

AB - The glycidyl azide polymer (GAP)/isophorone diisocyanate (IPDI) system and GAP-IPDI/prepolymer/nitrocellose (NC) system were prepared. Their curing reaction kinetics was studied by FT-IR. The experimental results show that the reaction rates of the two systems increase with an increase in temperature. When the content of the curing catalyst T12 is 0.025%, the apparent activation energy of the curing reaction for the two systems are 64.88 kJ/mol and 111.19 kJ/mol, respectively, and the reaction appeares as second-order kinetic reaction.

KW - Curing reaction kinetics

KW - FT-IR spectrum

KW - Glycidyl azide polymer

KW - IPDI

KW - Isophorone diisocyanate

KW - Nitrocellos

KW - Physical chemistry

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M3 - Article

AN - SCOPUS:84876300151

SN - 1007-7812

VL - 36

SP - 43

EP - 46

JO - Huozhayao Xuebao/Chinese Journal of Explosives and Propellants

JF - Huozhayao Xuebao/Chinese Journal of Explosives and Propellants

IS - 1

ER -

FT-IR study on the curing reaction of isophorone diisocyanate with the glycidyl azide polymer and its prepolymer with nitrocellose

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