Formyl azido substituted nitro hexaazaisowurtzitane-synthesis, characterization and energetic properties

Kai Dong, Yuan Wang, Xu Bin Gong, Jing Zhang, Cheng Hui Sun*, Si Ping Pang

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

Formyl azido substituted nitro hexaazaisowurtzitane derivatives, 2,4,6,8,12-pentanitro-10-formylazido-hexaazaisowurtzitane and 2,6,8,12-tetranitro-4,10-diformylazido-hexaazaisowurtzitane, have been synthesized and well characterized by IR and NMR (1H, 13C) spectroscopy, mass spectroscopy (MS), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and single-crystal X-ray diffraction. Their key properties such as melting points and decomposition temperatures, densities, dissociation energy of bonds (BDE), electrostatic potential (ESP), impact sensitivity (IS), detonation pressures (P) and velocities (D) were measured or calculated, which indicated an excellent combination of admirable detonation performance and stability as potential energetic compounds.

Original languageEnglish
Pages (from-to)3685-3691
Number of pages7
JournalNew Journal of Chemistry
Volume37
Issue number11
DOIs
Publication statusPublished - Nov 2013

Fingerprint

Dive into the research topics of 'Formyl azido substituted nitro hexaazaisowurtzitane-synthesis, characterization and energetic properties'. Together they form a unique fingerprint.

Cite this