Formation of a new layered aluminophosphate [Al3P4O16] [C5N2H9]2[NH4]

J. Yu; J. Li; K. Sugiyama; N. Togashi; O. Terasaki; K. Hiraga; B. Zhou; S. Qiu; R. Xu

doi:10.1021/cm981095v

Formation of a new layered aluminophosphate [Al₃P₄O₁₆] [C₅N₂H₉]₂[NH₄]

J. Yu^*, J. Li, K. Sugiyama, N. Togashi, O. Terasaki, K. Hiraga, B. Zhou, S. Qiu, R. Xu

^*Corresponding author for this work

Tohoku University

Research output: Contribution to journal › Article › peer-review

50 Citations (Scopus)

Abstract

A new layered aluminophosphate [Al₃P₄O₁₆][C₅N₂H ₉]₂[NH₄] (1) has been crystallized in a gel system with molar ratio of Al(PrOⁱ)₃:3.6 H₃PO₄:5.9 l,2-dimethylimidazole:12 TEG:3.4 H₂O at 180 °C. Its structure is solved by single-crystal X-ray diffraction analysis. Compound 1 crystallizes in the monoclinic space group P2₁/c (no. 14), with a = 10.402(1), b = 14.545(1), c = 16.361(1) Å, β= 96.397(6)°, and Z = 4. The inorganic layers, which are constructed from alternating tetrahedral AlO₄ and PO₃(=O) units, contain 4.6 nets and are featured by a series of ◇₃(Tp)₅ chains. The layers are further held together through strong H-bonds between the terminal oxygen groups and ammonium cations NH₄⁺ as well as protonated 1,2-dimethylimidazole molecules located in the interlayer. Formation of the 4.6 nets of 1 can be thought as the condensation of ◇₃(Tp)₅ chains.

Original language	English
Pages (from-to)	1727-1732
Number of pages	6
Journal	Chemistry of Materials
Volume	11
Issue number	7
DOIs	https://doi.org/10.1021/cm981095v
Publication status	Published - 1999
Externally published	Yes

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@article{85e7980928084dcaafd835f4c89bada8,

title = "Formation of a new layered aluminophosphate [Al3P4O16] [C5N2H9]2[NH4]",

abstract = "A new layered aluminophosphate [Al3P4O16][C5N2H 9]2[NH4] (1) has been crystallized in a gel system with molar ratio of Al(PrOi)3:3.6 H3PO4:5.9 l,2-dimethylimidazole:12 TEG:3.4 H2O at 180 °C. Its structure is solved by single-crystal X-ray diffraction analysis. Compound 1 crystallizes in the monoclinic space group P21/c (no. 14), with a = 10.402(1), b = 14.545(1), c = 16.361(1) {\AA}, β= 96.397(6)°, and Z = 4. The inorganic layers, which are constructed from alternating tetrahedral AlO4 and PO3(=O) units, contain 4.6 nets and are featured by a series of ◇3(Tp)5 chains. The layers are further held together through strong H-bonds between the terminal oxygen groups and ammonium cations NH4+ as well as protonated 1,2-dimethylimidazole molecules located in the interlayer. Formation of the 4.6 nets of 1 can be thought as the condensation of ◇3(Tp)5 chains.",

author = "J. Yu and J. Li and K. Sugiyama and N. Togashi and O. Terasaki and K. Hiraga and B. Zhou and S. Qiu and R. Xu",

year = "1999",

doi = "10.1021/cm981095v",

language = "English",

volume = "11",

pages = "1727--1732",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society",

number = "7",

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TY - JOUR

T1 - Formation of a new layered aluminophosphate [Al3P4O16] [C5N2H9]2[NH4]

AU - Yu, J.

AU - Li, J.

AU - Sugiyama, K.

AU - Togashi, N.

AU - Terasaki, O.

AU - Hiraga, K.

AU - Zhou, B.

AU - Qiu, S.

AU - Xu, R.

PY - 1999

Y1 - 1999

N2 - A new layered aluminophosphate [Al3P4O16][C5N2H 9]2[NH4] (1) has been crystallized in a gel system with molar ratio of Al(PrOi)3:3.6 H3PO4:5.9 l,2-dimethylimidazole:12 TEG:3.4 H2O at 180 °C. Its structure is solved by single-crystal X-ray diffraction analysis. Compound 1 crystallizes in the monoclinic space group P21/c (no. 14), with a = 10.402(1), b = 14.545(1), c = 16.361(1) Å, β= 96.397(6)°, and Z = 4. The inorganic layers, which are constructed from alternating tetrahedral AlO4 and PO3(=O) units, contain 4.6 nets and are featured by a series of ◇3(Tp)5 chains. The layers are further held together through strong H-bonds between the terminal oxygen groups and ammonium cations NH4+ as well as protonated 1,2-dimethylimidazole molecules located in the interlayer. Formation of the 4.6 nets of 1 can be thought as the condensation of ◇3(Tp)5 chains.

AB - A new layered aluminophosphate [Al3P4O16][C5N2H 9]2[NH4] (1) has been crystallized in a gel system with molar ratio of Al(PrOi)3:3.6 H3PO4:5.9 l,2-dimethylimidazole:12 TEG:3.4 H2O at 180 °C. Its structure is solved by single-crystal X-ray diffraction analysis. Compound 1 crystallizes in the monoclinic space group P21/c (no. 14), with a = 10.402(1), b = 14.545(1), c = 16.361(1) Å, β= 96.397(6)°, and Z = 4. The inorganic layers, which are constructed from alternating tetrahedral AlO4 and PO3(=O) units, contain 4.6 nets and are featured by a series of ◇3(Tp)5 chains. The layers are further held together through strong H-bonds between the terminal oxygen groups and ammonium cations NH4+ as well as protonated 1,2-dimethylimidazole molecules located in the interlayer. Formation of the 4.6 nets of 1 can be thought as the condensation of ◇3(Tp)5 chains.

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DO - 10.1021/cm981095v

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VL - 11

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JF - Chemistry of Materials

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Formation of a new layered aluminophosphate [Al₃P₄O₁₆] [C₅N₂H₉]₂[NH₄]

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