TY - JOUR
T1 - Flash pyrolysis study of 2, 4, 6-trinitroresorcinol (TNR) metallic (kalium, cesium, argentum) compounds
AU - Zhang, Qiang
AU - Qiao, Xiao Jing
AU - Zhang, Jian Guo
AU - Shang, Jing
PY - 2014/1
Y1 - 2014/1
N2 - Rapid thermolysis Styphnic acid (TNR) compounds (kalium, cesium, argentum) were studied by T-jump/FTIR spectroscopy. The species of the volatile metal compounds which are liberated in the processes of the flash pyrolysis of Styphnic acid (TNR) compounds (kalium, cesium, and argentum) were determined. In addition, the three-dimensional and planar spectrogram of main IR-active gas products were obtained. We also got the change curve which delegated the concentration of gas productions along with time and reactive equations in the process of flash pyrolysis. The qualitative and quantitative analysis of main IR-active gas products from flash pyrolysis of these compounds were accomplished, furthermore, the thermal decomposition mechanism was derived.
AB - Rapid thermolysis Styphnic acid (TNR) compounds (kalium, cesium, argentum) were studied by T-jump/FTIR spectroscopy. The species of the volatile metal compounds which are liberated in the processes of the flash pyrolysis of Styphnic acid (TNR) compounds (kalium, cesium, and argentum) were determined. In addition, the three-dimensional and planar spectrogram of main IR-active gas products were obtained. We also got the change curve which delegated the concentration of gas productions along with time and reactive equations in the process of flash pyrolysis. The qualitative and quantitative analysis of main IR-active gas products from flash pyrolysis of these compounds were accomplished, furthermore, the thermal decomposition mechanism was derived.
KW - 2, 4, 6-trinitroresorcinol
KW - Flash pyrolysis
KW - T-jump/FTIR spectroscopy
UR - http://www.scopus.com/inward/record.url?scp=84897696855&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:84897696855
SN - 0254-0037
VL - 40
SP - 80
EP - 84
JO - Beijing Gongye Daxue Xuebao / Journal of Beijing University of Technology
JF - Beijing Gongye Daxue Xuebao / Journal of Beijing University of Technology
IS - 1
ER -