Fabrication of SAPO-34 crystals with different morphologies by microwave heating

Song Lin; Jiyang Li; Raj Pal Sharma; Jihong Yu; Ruren Xu

doi:10.1007/s11244-010-9588-3

Fabrication of SAPO-34 crystals with different morphologies by microwave heating

Song Lin, Jiyang Li, Raj Pal Sharma, Jihong Yu^*, Ruren Xu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

97 Citations (Scopus)

Abstract

The crystal size and shape of the silicoaluminophosphate molecular sieve SAPO-34 have been effectively controlled in the reaction system of Al ₂O₃-P₂O₅-SiO₂-TEAOH- H₂O under microwave radiations. Nano sheet-like SAPO-34 crystals are obtained when using colloidal silica as the silica source. When TEOS is used as the source of silica, homogeneous SAPO-34 crystals with a particle size of about 100 nm are formed, and the morphology of the crystals changes from uniform nano particles (∼100 nm) to microspheres (∼ 1.5 μm) by varying the H ₂O/Al₂O₃ molar ratio. To further investigate the morphology control of SAPO-34, the synthetic factors, such as the silica source, water content, crystallization time and aging time have been studied in detail.

Original language	English
Pages (from-to)	1304-1310
Number of pages	7
Journal	Topics in Catalysis
Volume	53
Issue number	19-20
DOIs	https://doi.org/10.1007/s11244-010-9588-3
Publication status	Published - Dec 2010
Externally published	Yes

Keywords

Microwave heating
Morphology
SAPO-34
Zeolite

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10.1007/s11244-010-9588-3

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title = "Fabrication of SAPO-34 crystals with different morphologies by microwave heating",

abstract = "The crystal size and shape of the silicoaluminophosphate molecular sieve SAPO-34 have been effectively controlled in the reaction system of Al 2O3-P2O5-SiO2-TEAOH- H2O under microwave radiations. Nano sheet-like SAPO-34 crystals are obtained when using colloidal silica as the silica source. When TEOS is used as the source of silica, homogeneous SAPO-34 crystals with a particle size of about 100 nm are formed, and the morphology of the crystals changes from uniform nano particles (∼100 nm) to microspheres (∼ 1.5 μm) by varying the H 2O/Al2O3 molar ratio. To further investigate the morphology control of SAPO-34, the synthetic factors, such as the silica source, water content, crystallization time and aging time have been studied in detail.",

keywords = "Microwave heating, Morphology, SAPO-34, Zeolite",

author = "Song Lin and Jiyang Li and Sharma, {Raj Pal} and Jihong Yu and Ruren Xu",

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language = "English",

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TY - JOUR

T1 - Fabrication of SAPO-34 crystals with different morphologies by microwave heating

AU - Lin, Song

AU - Li, Jiyang

AU - Sharma, Raj Pal

AU - Yu, Jihong

AU - Xu, Ruren

PY - 2010/12

Y1 - 2010/12

N2 - The crystal size and shape of the silicoaluminophosphate molecular sieve SAPO-34 have been effectively controlled in the reaction system of Al 2O3-P2O5-SiO2-TEAOH- H2O under microwave radiations. Nano sheet-like SAPO-34 crystals are obtained when using colloidal silica as the silica source. When TEOS is used as the source of silica, homogeneous SAPO-34 crystals with a particle size of about 100 nm are formed, and the morphology of the crystals changes from uniform nano particles (∼100 nm) to microspheres (∼ 1.5 μm) by varying the H 2O/Al2O3 molar ratio. To further investigate the morphology control of SAPO-34, the synthetic factors, such as the silica source, water content, crystallization time and aging time have been studied in detail.

AB - The crystal size and shape of the silicoaluminophosphate molecular sieve SAPO-34 have been effectively controlled in the reaction system of Al 2O3-P2O5-SiO2-TEAOH- H2O under microwave radiations. Nano sheet-like SAPO-34 crystals are obtained when using colloidal silica as the silica source. When TEOS is used as the source of silica, homogeneous SAPO-34 crystals with a particle size of about 100 nm are formed, and the morphology of the crystals changes from uniform nano particles (∼100 nm) to microspheres (∼ 1.5 μm) by varying the H 2O/Al2O3 molar ratio. To further investigate the morphology control of SAPO-34, the synthetic factors, such as the silica source, water content, crystallization time and aging time have been studied in detail.

KW - Microwave heating

KW - Morphology

KW - SAPO-34

KW - Zeolite

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U2 - 10.1007/s11244-010-9588-3

DO - 10.1007/s11244-010-9588-3

M3 - Article

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SN - 1022-5528

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SP - 1304

EP - 1310

JO - Topics in Catalysis

JF - Topics in Catalysis

IS - 19-20

ER -

Fabrication of SAPO-34 crystals with different morphologies by microwave heating

Abstract

Keywords

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