Electrostatic Interaction Tailored Anion-Rich Solvation Sheath Stabilizing High-Voltage Lithium Metal Batteries

Junru Wu; Ziyao Gao; Yao Wang; Xu Yang; Qi Liu; Dong Zhou; Xianshu Wang; Feiyu Kang; Baohua Li

doi:10.1007/s40820-022-00896-4

Electrostatic Interaction Tailored Anion-Rich Solvation Sheath Stabilizing High-Voltage Lithium Metal Batteries

Junru Wu, Ziyao Gao, Yao Wang, Xu Yang, Qi Liu, Dong Zhou, Xianshu Wang^*, Feiyu Kang, Baohua Li^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

48 Citations (Scopus)

Abstract

The effect of electrostatic interaction on regulating an anion-rich solvation in electrolyte is firstly proposed.The moderate electrostatic interaction between anion and solvent promotes anion-rich solvation sheath, inducing a stable electrolyte|electrode interface with fast Li⁺ transport kinetics.The outstanding electrochemical performance of 50 μm-thin Li||high-loading LiCoO₂ batteries is achieved at high voltage of 4.5 V (even up to 4.6 V), lean electrolyte of 15 μL, and wide temperature range of − 20 to 60 °C.

Original language	English
Article number	147
Journal	Nano-Micro Letters
Volume	14
Issue number	1
DOIs	https://doi.org/10.1007/s40820-022-00896-4
Publication status	Published - Dec 2022
Externally published	Yes

Keywords

Anion-rich solvation sheath
Electrostatic interaction
High voltage
Lithium metal batteries
Wide temperature range

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10.1007/s40820-022-00896-4

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Wu, J., Gao, Z., Wang, Y., Yang, X., Liu, Q., Zhou, D., Wang, X., Kang, F., & Li, B. (2022). Electrostatic Interaction Tailored Anion-Rich Solvation Sheath Stabilizing High-Voltage Lithium Metal Batteries. Nano-Micro Letters, 14(1), Article 147. https://doi.org/10.1007/s40820-022-00896-4

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abstract = "The effect of electrostatic interaction on regulating an anion-rich solvation in electrolyte is firstly proposed.The moderate electrostatic interaction between anion and solvent promotes anion-rich solvation sheath, inducing a stable electrolyte|electrode interface with fast Li+ transport kinetics.The outstanding electrochemical performance of 50 μm-thin Li||high-loading LiCoO2 batteries is achieved at high voltage of 4.5 V (even up to 4.6 V), lean electrolyte of 15 μL, and wide temperature range of − 20 to 60 °C.",

keywords = "Anion-rich solvation sheath, Electrostatic interaction, High voltage, Lithium metal batteries, Wide temperature range",

author = "Junru Wu and Ziyao Gao and Yao Wang and Xu Yang and Qi Liu and Dong Zhou and Xianshu Wang and Feiyu Kang and Baohua Li",

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year = "2022",

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doi = "10.1007/s40820-022-00896-4",

language = "English",

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AU - Wu, Junru

AU - Gao, Ziyao

AU - Wang, Yao

AU - Yang, Xu

AU - Liu, Qi

AU - Zhou, Dong

AU - Wang, Xianshu

AU - Kang, Feiyu

AU - Li, Baohua

PY - 2022/12

Y1 - 2022/12

N2 - The effect of electrostatic interaction on regulating an anion-rich solvation in electrolyte is firstly proposed.The moderate electrostatic interaction between anion and solvent promotes anion-rich solvation sheath, inducing a stable electrolyte|electrode interface with fast Li+ transport kinetics.The outstanding electrochemical performance of 50 μm-thin Li||high-loading LiCoO2 batteries is achieved at high voltage of 4.5 V (even up to 4.6 V), lean electrolyte of 15 μL, and wide temperature range of − 20 to 60 °C.

AB - The effect of electrostatic interaction on regulating an anion-rich solvation in electrolyte is firstly proposed.The moderate electrostatic interaction between anion and solvent promotes anion-rich solvation sheath, inducing a stable electrolyte|electrode interface with fast Li+ transport kinetics.The outstanding electrochemical performance of 50 μm-thin Li||high-loading LiCoO2 batteries is achieved at high voltage of 4.5 V (even up to 4.6 V), lean electrolyte of 15 μL, and wide temperature range of − 20 to 60 °C.

KW - Anion-rich solvation sheath

KW - Electrostatic interaction

KW - High voltage

KW - Lithium metal batteries

KW - Wide temperature range

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DO - 10.1007/s40820-022-00896-4

M3 - Article

AN - SCOPUS:85134596559

SN - 2311-6706

VL - 14

JO - Nano-Micro Letters

JF - Nano-Micro Letters

IS - 1

M1 - 147

ER -

Electrostatic Interaction Tailored Anion-Rich Solvation Sheath Stabilizing High-Voltage Lithium Metal Batteries

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