Dynamic vacuum stability test method for thermal decomposition of CL-20

Rui Liu; Yan Li Yin; Tong Lai Zhang; Li Yang; Jian Guo Zhang; Zun Ning Zhou; Xiao Jing Qiao; Wen Jie Wang; Li Qiong Wang

Dynamic vacuum stability test method for thermal decomposition of CL-20

Rui Liu^*, Yan Li Yin, Tong Lai Zhang, Li Yang, Jian Guo Zhang, Zun Ning Zhou, Xiao Jing Qiao, Wen Jie Wang, Li Qiong Wang

^*Corresponding author for this work

School of Mechatronical Engineering

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The thermal decomposition of CL-20 was investigated by dynamic vacuum stability test (DVST). The results show that the mechanism function of non-isothermal decomposition of CL-20 is Avrami-Erofeev equation with n = 4. The apparent activation energy E, is 165. 3 kj · mol^-1, and the pre-exponential factor In (A/s^-1 ) is 40. 20. Isothermal decomposition mechanism function changes with temperature, the reaction rate constant increases exponentially with temperature from 1. 01 × 10 ^-6 s^-1 at 90°C to 1. 81 × 10^-s s ^-1 at 140 °C. The amount of decomposition gases of CL-20 tested at 100°C is 0. 502 mL ·; g^-1 , showing that the thermal stability of CL-20 is better. By fitting the Semenov equation, the effective storage life of CL-20 at 25°C is 14. 4 a.

Original language	English
Pages (from-to)	21-25
Number of pages	5
Journal	Huozhayao Xuebao/Chinese Journal of Explosives and Propellants
Volume	34
Issue number	2
Publication status	Published - 2011

Keywords

CL-20
Kinetic parameter
Physical chemistry;dynamic vacuum stability test
Thermal stability; storage life

Cite this

@article{6acf208c78ab4c7795e8b37ee66315be,

title = "Dynamic vacuum stability test method for thermal decomposition of CL-20",

abstract = "The thermal decomposition of CL-20 was investigated by dynamic vacuum stability test (DVST). The results show that the mechanism function of non-isothermal decomposition of CL-20 is Avrami-Erofeev equation with n = 4. The apparent activation energy E, is 165. 3 kj · mol-1, and the pre-exponential factor In (A/s-1 ) is 40. 20. Isothermal decomposition mechanism function changes with temperature, the reaction rate constant increases exponentially with temperature from 1. 01 × 10 -6 s-1 at 90°C to 1. 81 × 10-s s -1 at 140 °C. The amount of decomposition gases of CL-20 tested at 100°C is 0. 502 mL ·; g-1 , showing that the thermal stability of CL-20 is better. By fitting the Semenov equation, the effective storage life of CL-20 at 25°C is 14. 4 a.",

keywords = "CL-20, Kinetic parameter, Physical chemistry;dynamic vacuum stability test, Thermal stability; storage life",

author = "Rui Liu and Yin, {Yan Li} and Zhang, {Tong Lai} and Li Yang and Zhang, {Jian Guo} and Zhou, {Zun Ning} and Qiao, {Xiao Jing} and Wang, {Wen Jie} and Wang, {Li Qiong}",

year = "2011",

language = "English",

volume = "34",

pages = "21--25",

journal = "Huozhayao Xuebao/Chinese Journal of Explosives and Propellants",

issn = "1007-7812",

publisher = "China Ordnance Industry Corporation",

number = "2",

}

TY - JOUR

T1 - Dynamic vacuum stability test method for thermal decomposition of CL-20

AU - Liu, Rui

AU - Yin, Yan Li

AU - Zhang, Tong Lai

AU - Yang, Li

AU - Zhang, Jian Guo

AU - Zhou, Zun Ning

AU - Qiao, Xiao Jing

AU - Wang, Wen Jie

AU - Wang, Li Qiong

PY - 2011

Y1 - 2011

N2 - The thermal decomposition of CL-20 was investigated by dynamic vacuum stability test (DVST). The results show that the mechanism function of non-isothermal decomposition of CL-20 is Avrami-Erofeev equation with n = 4. The apparent activation energy E, is 165. 3 kj · mol-1, and the pre-exponential factor In (A/s-1 ) is 40. 20. Isothermal decomposition mechanism function changes with temperature, the reaction rate constant increases exponentially with temperature from 1. 01 × 10 -6 s-1 at 90°C to 1. 81 × 10-s s -1 at 140 °C. The amount of decomposition gases of CL-20 tested at 100°C is 0. 502 mL ·; g-1 , showing that the thermal stability of CL-20 is better. By fitting the Semenov equation, the effective storage life of CL-20 at 25°C is 14. 4 a.

AB - The thermal decomposition of CL-20 was investigated by dynamic vacuum stability test (DVST). The results show that the mechanism function of non-isothermal decomposition of CL-20 is Avrami-Erofeev equation with n = 4. The apparent activation energy E, is 165. 3 kj · mol-1, and the pre-exponential factor In (A/s-1 ) is 40. 20. Isothermal decomposition mechanism function changes with temperature, the reaction rate constant increases exponentially with temperature from 1. 01 × 10 -6 s-1 at 90°C to 1. 81 × 10-s s -1 at 140 °C. The amount of decomposition gases of CL-20 tested at 100°C is 0. 502 mL ·; g-1 , showing that the thermal stability of CL-20 is better. By fitting the Semenov equation, the effective storage life of CL-20 at 25°C is 14. 4 a.

KW - CL-20

KW - Kinetic parameter

KW - Physical chemistry;dynamic vacuum stability test

KW - Thermal stability; storage life

UR - http://www.scopus.com/inward/record.url?scp=79958728993&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:79958728993

SN - 1007-7812

VL - 34

SP - 21

EP - 25

JO - Huozhayao Xuebao/Chinese Journal of Explosives and Propellants

JF - Huozhayao Xuebao/Chinese Journal of Explosives and Propellants

IS - 2

ER -

Dynamic vacuum stability test method for thermal decomposition of CL-20

Abstract

Keywords

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