Direct synthesis, crystal structures and thermal analyses of the two-dimensional Cu(ntp)2(H2O)4 crystal (ntp=2-nitroterephthalate)

Jin Yu Guo; Tong Lai Zhang; Jian Guo Zhang; Yan Hong Liu; Kai Bei Yu

Direct synthesis, crystal structures and thermal analyses of the two-dimensional Cu(ntp)₂(H₂O)₄ crystal (ntp=2-nitroterephthalate)

Jin Yu Guo^*, Tong Lai Zhang, Jian Guo Zhang, Yan Hong Liu, Kai Bei Yu

^*Corresponding author for this work

School of Mechatronical Engineering

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The Cu(ntp)₂(H₂O)₄ coordination compound has been synthesized by direct method and its crystal has been cultured and characterized by X-ray single crystal structural analysis. The crystal is formulated as C₁₆H₁₆CuN₂O₁₆ and crystallized in monoclinic system, space group C2/c, with a=2.2665(7) nm, b=0.7068(2) nm, c=1.575 5(4) nm, β=126.42(1)°, V=2.030 8(13) nm ³, D_c=1.818 g·cm³. Based on DSC and TG-DTG analyses, the thermal decomposition mechanism of Cu(ntp) ₂(H₂O)₄ is predicted that it loses its four coordinated water molecules followed by a large weight loss and formation of copper oxide on heating.

Original language	English
Pages (from-to)	995-999
Number of pages	5
Journal	Chinese Journal of Inorganic Chemistry
Volume	22
Issue number	6
Publication status	Published - Jun 2006

Keywords

Crystal structure
Direct synthesis
Thermal decomposition

Cite this

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title = "Direct synthesis, crystal structures and thermal analyses of the two-dimensional Cu(ntp)2(H2O)4 crystal (ntp=2-nitroterephthalate)",

abstract = "The Cu(ntp)2(H2O)4 coordination compound has been synthesized by direct method and its crystal has been cultured and characterized by X-ray single crystal structural analysis. The crystal is formulated as C16H16CuN2O16 and crystallized in monoclinic system, space group C2/c, with a=2.2665(7) nm, b=0.7068(2) nm, c=1.575 5(4) nm, β=126.42(1)°, V=2.030 8(13) nm 3, Dc=1.818 g·cm3. Based on DSC and TG-DTG analyses, the thermal decomposition mechanism of Cu(ntp) 2(H2O)4 is predicted that it loses its four coordinated water molecules followed by a large weight loss and formation of copper oxide on heating.",

keywords = "Crystal structure, Direct synthesis, Thermal decomposition",

author = "Guo, {Jin Yu} and Zhang, {Tong Lai} and Zhang, {Jian Guo} and Liu, {Yan Hong} and Yu, {Kai Bei}",

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journal = "Chinese Journal of Inorganic Chemistry",

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T1 - Direct synthesis, crystal structures and thermal analyses of the two-dimensional Cu(ntp)2(H2O)4 crystal (ntp=2-nitroterephthalate)

AU - Guo, Jin Yu

AU - Zhang, Tong Lai

AU - Zhang, Jian Guo

AU - Liu, Yan Hong

AU - Yu, Kai Bei

PY - 2006/6

Y1 - 2006/6

N2 - The Cu(ntp)2(H2O)4 coordination compound has been synthesized by direct method and its crystal has been cultured and characterized by X-ray single crystal structural analysis. The crystal is formulated as C16H16CuN2O16 and crystallized in monoclinic system, space group C2/c, with a=2.2665(7) nm, b=0.7068(2) nm, c=1.575 5(4) nm, β=126.42(1)°, V=2.030 8(13) nm 3, Dc=1.818 g·cm3. Based on DSC and TG-DTG analyses, the thermal decomposition mechanism of Cu(ntp) 2(H2O)4 is predicted that it loses its four coordinated water molecules followed by a large weight loss and formation of copper oxide on heating.

AB - The Cu(ntp)2(H2O)4 coordination compound has been synthesized by direct method and its crystal has been cultured and characterized by X-ray single crystal structural analysis. The crystal is formulated as C16H16CuN2O16 and crystallized in monoclinic system, space group C2/c, with a=2.2665(7) nm, b=0.7068(2) nm, c=1.575 5(4) nm, β=126.42(1)°, V=2.030 8(13) nm 3, Dc=1.818 g·cm3. Based on DSC and TG-DTG analyses, the thermal decomposition mechanism of Cu(ntp) 2(H2O)4 is predicted that it loses its four coordinated water molecules followed by a large weight loss and formation of copper oxide on heating.

KW - Crystal structure

KW - Direct synthesis

KW - Thermal decomposition

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M3 - Article

AN - SCOPUS:33745603022

SN - 1001-4861

VL - 22

SP - 995

EP - 999

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 6

ER -

Direct synthesis, crystal structures and thermal analyses of the two-dimensional Cu(ntp)₂(H₂O)₄ crystal (ntp=2-nitroterephthalate)

Abstract

Keywords

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