TY - JOUR
T1 - Controlling placement of nonspherical (boomerang) colloids in nematic cells with photopatterned director
AU - Peng, Chenhui
AU - Turiv, Taras
AU - Zhang, Rui
AU - Guo, Yubing
AU - Shiyanovskii, Sergij V.
AU - Wei, Qi Huo
AU - De Pablo, Juan
AU - Lavrentovich, Oleg D.
N1 - Publisher Copyright:
© 2016 IOP Publishing Ltd.
PY - 2017/11/1
Y1 - 2017/11/1
N2 - Placing colloidal particles in predesigned sites represents a major challenge of the current state-of-the-art colloidal science. Nematic liquid crystals with spatially varying director patterns represent a promising approach to achieve a well-controlled placement of colloidal particles thanks to the elastic forces between the particles and the surrounding landscape of molecular orientation. Here we demonstrate how the spatially varying director field can be used to control placement of non-spherical particles of boomerang shape. The boomerang colloids create director distortions of a dipolar symmetry. When a boomerang particle is placed in a periodic splay-bend director pattern, it migrates towards the region of a maximum bend. The behavior is contrasted to that one of spherical particles with normal surface anchoring, which also produce dipolar director distortions, but prefer to compartmentalize into the regions with a maximum splay. The splay-bend periodic landscape thus allows one to spatially separate these two types of particles. By exploring overdamped dynamics of the colloids, we determine elastic driving forces responsible for the preferential placement. Control of colloidal locations through patterned molecular orientation can be explored for future applications in microfluidic, lab on a chip, sensing and sorting devices.
AB - Placing colloidal particles in predesigned sites represents a major challenge of the current state-of-the-art colloidal science. Nematic liquid crystals with spatially varying director patterns represent a promising approach to achieve a well-controlled placement of colloidal particles thanks to the elastic forces between the particles and the surrounding landscape of molecular orientation. Here we demonstrate how the spatially varying director field can be used to control placement of non-spherical particles of boomerang shape. The boomerang colloids create director distortions of a dipolar symmetry. When a boomerang particle is placed in a periodic splay-bend director pattern, it migrates towards the region of a maximum bend. The behavior is contrasted to that one of spherical particles with normal surface anchoring, which also produce dipolar director distortions, but prefer to compartmentalize into the regions with a maximum splay. The splay-bend periodic landscape thus allows one to spatially separate these two types of particles. By exploring overdamped dynamics of the colloids, we determine elastic driving forces responsible for the preferential placement. Control of colloidal locations through patterned molecular orientation can be explored for future applications in microfluidic, lab on a chip, sensing and sorting devices.
KW - liquid crystal
KW - nonspherical colloid
KW - photopatterned director
KW - placement
UR - http://www.scopus.com/inward/record.url?scp=85000702965&partnerID=8YFLogxK
U2 - 10.1088/0953-8984/29/1/014005
DO - 10.1088/0953-8984/29/1/014005
M3 - Article
C2 - 27830662
AN - SCOPUS:85000702965
SN - 0953-8984
VL - 29
JO - Journal of Physics Condensed Matter
JF - Journal of Physics Condensed Matter
IS - 1
M1 - 014005
ER -