Co-templated synthesis and characterization of two new 1D zincophosphates, [CoIII(dien)2][Zn(PO4)(HPO4)] Â·H3BO3 and [CoIII (dien) 2][Zn2(PO4)(HPO4) 2]Â·C2H6O2

You Ju Zhong; Yong Mei Chen; Yan Qiong Sun; Guo Yu Yang

doi:10.1039/b501595b

Co-templated synthesis and characterization of two new 1D zincophosphates, [Co^III(dien)₂][Zn(PO₄)(HPO₄)] Â·H₃BO₃ and [Co^III (dien) ₂][Zn₂(PO₄)(HPO₄) ₂]Â·C₂H₆O₂

You Ju Zhong, Yong Mei Chen, Yan Qiong Sun, Guo Yu Yang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Two 1-D zincophosphates, [Co^III(dien)₂][Zn(PO ₄)(HPO₄)]Â·H₃BO₃ (1) and [Co^III(dien)₂][Zn₂(PO₄)(HPO ₄)₂]Â·C₂H₆O ₂ (2), have been synthesized under solvothermal conditions at 130 Â°C. Their structures were determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis and TG analysis. The structures of 1 and 2 consist of ZnO₄, PO₄ and HPO₄ tetrahedra with sharing corners, forming strictly alternate four-membered rings for 1 and the 4 = 1 secondary building units for 2. The adjacent chains in 1 and 2 are further connected into 2-D and 3-D networks by ionic interactions and hydrogen bonds. The complex cation, s-cis Co(dien) ₂ ³⁺ and neutral molecule, boric acid dimer linked through H-bonds for 1 and ethylene glycol (EG) for 2, co-play the roles of structure-directing agents in the formation of the inorganic networks of 1 and 2, respectively.

Original language	English
Article number	37
Pages (from-to)	237-242
Number of pages	6
Journal	CrystEngComm
Volume	7
DOIs	https://doi.org/10.1039/b501595b
Publication status	Published - 23 Mar 2005
Externally published	Yes

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@article{3e6e25f1f89d4335ac4654e1930c562b,

title = "Co-templated synthesis and characterization of two new 1D zincophosphates, [CoIII(dien)2][Zn(PO4)(HPO4)] {\^A}·H3BO3 and [CoIII (dien) 2][Zn2(PO4)(HPO4) 2]{\^A}·C2H6O2 ",

abstract = "Two 1-D zincophosphates, [CoIII(dien)2][Zn(PO 4)(HPO4)]{\^A}·H3BO3 (1) and [CoIII(dien)2][Zn2(PO4)(HPO 4)2]{\^A}·C2H6O 2 (2), have been synthesized under solvothermal conditions at 130 {\^A}°C. Their structures were determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis and TG analysis. The structures of 1 and 2 consist of ZnO4, PO4 and HPO4 tetrahedra with sharing corners, forming strictly alternate four-membered rings for 1 and the 4 = 1 secondary building units for 2. The adjacent chains in 1 and 2 are further connected into 2-D and 3-D networks by ionic interactions and hydrogen bonds. The complex cation, s-cis Co(dien) 2 3+ and neutral molecule, boric acid dimer linked through H-bonds for 1 and ethylene glycol (EG) for 2, co-play the roles of structure-directing agents in the formation of the inorganic networks of 1 and 2, respectively.",

author = "Zhong, {You Ju} and Chen, {Yong Mei} and Sun, {Yan Qiong} and Yang, {Guo Yu}",

year = "2005",

month = mar,

day = "23",

doi = "10.1039/b501595b",

language = "English",

volume = "7",

pages = "237--242",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - Co-templated synthesis and characterization of two new 1D zincophosphates, [CoIII(dien)2][Zn(PO4)(HPO4)] Â·H3BO3 and [CoIII (dien) 2][Zn2(PO4)(HPO4) 2]Â·C2H6O2

AU - Zhong, You Ju

AU - Chen, Yong Mei

AU - Sun, Yan Qiong

AU - Yang, Guo Yu

PY - 2005/3/23

Y1 - 2005/3/23

N2 - Two 1-D zincophosphates, [CoIII(dien)2][Zn(PO 4)(HPO4)]Â·H3BO3 (1) and [CoIII(dien)2][Zn2(PO4)(HPO 4)2]Â·C2H6O 2 (2), have been synthesized under solvothermal conditions at 130 Â°C. Their structures were determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis and TG analysis. The structures of 1 and 2 consist of ZnO4, PO4 and HPO4 tetrahedra with sharing corners, forming strictly alternate four-membered rings for 1 and the 4 = 1 secondary building units for 2. The adjacent chains in 1 and 2 are further connected into 2-D and 3-D networks by ionic interactions and hydrogen bonds. The complex cation, s-cis Co(dien) 2 3+ and neutral molecule, boric acid dimer linked through H-bonds for 1 and ethylene glycol (EG) for 2, co-play the roles of structure-directing agents in the formation of the inorganic networks of 1 and 2, respectively.

AB - Two 1-D zincophosphates, [CoIII(dien)2][Zn(PO 4)(HPO4)]Â·H3BO3 (1) and [CoIII(dien)2][Zn2(PO4)(HPO 4)2]Â·C2H6O 2 (2), have been synthesized under solvothermal conditions at 130 Â°C. Their structures were determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis and TG analysis. The structures of 1 and 2 consist of ZnO4, PO4 and HPO4 tetrahedra with sharing corners, forming strictly alternate four-membered rings for 1 and the 4 = 1 secondary building units for 2. The adjacent chains in 1 and 2 are further connected into 2-D and 3-D networks by ionic interactions and hydrogen bonds. The complex cation, s-cis Co(dien) 2 3+ and neutral molecule, boric acid dimer linked through H-bonds for 1 and ethylene glycol (EG) for 2, co-play the roles of structure-directing agents in the formation of the inorganic networks of 1 and 2, respectively.

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U2 - 10.1039/b501595b

DO - 10.1039/b501595b

M3 - Article

AN - SCOPUS:18944377982

SN - 1466-8033

VL - 7

SP - 237

EP - 242

JO - CrystEngComm

JF - CrystEngComm

M1 - 37

ER -

Co-templated synthesis and characterization of two new 1D zincophosphates, [Co^III(dien)₂][Zn(PO₄)(HPO₄)] Â·H₃BO₃ and [Co^III (dien) ₂][Zn₂(PO₄)(HPO₄) ₂]Â·C₂H₆O₂

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