Ji, W., Yuan, H., Xue, B., Guerin, S., Li, H., Zhang, L., Liu, Y., Shimon, L. J. W., Si, M., Cao, Y., Wang, W., Thompson, D., Cai, K., Yang, R., & Gazit, E. (2022). Co-Assembly Induced Solid-State Stacking Transformation in Amino Acid-Based Crystals with Enhanced Physical Properties. Angewandte Chemie - International Edition, 61(17), Article e202201234. https://doi.org/10.1002/anie.202201234
Ji, Wei ; Yuan, Hui ; Xue, Bin et al. / Co-Assembly Induced Solid-State Stacking Transformation in Amino Acid-Based Crystals with Enhanced Physical Properties. In: Angewandte Chemie - International Edition. 2022 ; Vol. 61, No. 17.
@article{8494b42acf2742b28007050a1fd67bf9,
title = "Co-Assembly Induced Solid-State Stacking Transformation in Amino Acid-Based Crystals with Enhanced Physical Properties",
abstract = "The physical characteristics of supramolecular assemblies composed of small building blocks are dictated by molecular packing patterns in the solid-state. Yet, the structure–property correlation is still not fully understood. Herein, we report the unexpected cofacial to herringbone stacking transformation of a small aromatic bipyridine through co-assembly with acetylated glutamic acid. The unique solid-state structural transformation results in enhanced physical properties of the supramolecular organizations. The co-assembly methodology was further expanded to obtain diverse molecular packings by different bipyridine and acetylated amino acid derivatives. This study presents a feasible co-assembly approach to achieve the solid-state stacking transformation of supramolecular organization and opens up new opportunities to further explore the relationship between molecular arrangement and properties of supramolecular assemblies by crystal engineering.",
keywords = "Amino Acids, Co-Assembly, Stacking Modes, Supramolecular Chemistry",
author = "Wei Ji and Hui Yuan and Bin Xue and Sarah Guerin and Hui Li and Lei Zhang and Yanqing Liu and Shimon, {Linda J.W.} and Mingsu Si and Yi Cao and Wei Wang and Damien Thompson and Kaiyong Cai and Rusen Yang and Ehud Gazit",
note = "Publisher Copyright: {\textcopyright} 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.",
year = "2022",
month = apr,
day = "19",
doi = "10.1002/anie.202201234",
language = "English",
volume = "61",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "17",
}
Ji, W, Yuan, H, Xue, B, Guerin, S, Li, H, Zhang, L, Liu, Y, Shimon, LJW, Si, M, Cao, Y, Wang, W, Thompson, D, Cai, K, Yang, R & Gazit, E 2022, 'Co-Assembly Induced Solid-State Stacking Transformation in Amino Acid-Based Crystals with Enhanced Physical Properties', Angewandte Chemie - International Edition, vol. 61, no. 17, e202201234. https://doi.org/10.1002/anie.202201234
Co-Assembly Induced Solid-State Stacking Transformation in Amino Acid-Based Crystals with Enhanced Physical Properties. / Ji, Wei; Yuan, Hui; Xue, Bin et al.
In:
Angewandte Chemie - International Edition, Vol. 61, No. 17, e202201234, 19.04.2022.
Research output: Contribution to journal › Article › peer-review
TY - JOUR
T1 - Co-Assembly Induced Solid-State Stacking Transformation in Amino Acid-Based Crystals with Enhanced Physical Properties
AU - Ji, Wei
AU - Yuan, Hui
AU - Xue, Bin
AU - Guerin, Sarah
AU - Li, Hui
AU - Zhang, Lei
AU - Liu, Yanqing
AU - Shimon, Linda J.W.
AU - Si, Mingsu
AU - Cao, Yi
AU - Wang, Wei
AU - Thompson, Damien
AU - Cai, Kaiyong
AU - Yang, Rusen
AU - Gazit, Ehud
N1 - Publisher Copyright:
© 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
PY - 2022/4/19
Y1 - 2022/4/19
N2 - The physical characteristics of supramolecular assemblies composed of small building blocks are dictated by molecular packing patterns in the solid-state. Yet, the structure–property correlation is still not fully understood. Herein, we report the unexpected cofacial to herringbone stacking transformation of a small aromatic bipyridine through co-assembly with acetylated glutamic acid. The unique solid-state structural transformation results in enhanced physical properties of the supramolecular organizations. The co-assembly methodology was further expanded to obtain diverse molecular packings by different bipyridine and acetylated amino acid derivatives. This study presents a feasible co-assembly approach to achieve the solid-state stacking transformation of supramolecular organization and opens up new opportunities to further explore the relationship between molecular arrangement and properties of supramolecular assemblies by crystal engineering.
AB - The physical characteristics of supramolecular assemblies composed of small building blocks are dictated by molecular packing patterns in the solid-state. Yet, the structure–property correlation is still not fully understood. Herein, we report the unexpected cofacial to herringbone stacking transformation of a small aromatic bipyridine through co-assembly with acetylated glutamic acid. The unique solid-state structural transformation results in enhanced physical properties of the supramolecular organizations. The co-assembly methodology was further expanded to obtain diverse molecular packings by different bipyridine and acetylated amino acid derivatives. This study presents a feasible co-assembly approach to achieve the solid-state stacking transformation of supramolecular organization and opens up new opportunities to further explore the relationship between molecular arrangement and properties of supramolecular assemblies by crystal engineering.
KW - Amino Acids
KW - Co-Assembly
KW - Stacking Modes
KW - Supramolecular Chemistry
UR - http://www.scopus.com/inward/record.url?scp=85125523487&partnerID=8YFLogxK
U2 - 10.1002/anie.202201234
DO - 10.1002/anie.202201234
M3 - Article
C2 - 35170170
AN - SCOPUS:85125523487
SN - 1433-7851
VL - 61
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 17
M1 - e202201234
ER -
Ji W, Yuan H, Xue B, Guerin S, Li H, Zhang L et al. Co-Assembly Induced Solid-State Stacking Transformation in Amino Acid-Based Crystals with Enhanced Physical Properties. Angewandte Chemie - International Edition. 2022 Apr 19;61(17):e202201234. doi: 10.1002/anie.202201234
