Cis-1,4-polymerization of isoprene by 1,3-bis(oxazolinymethylidene)isoindoline-ligated rare-earth metal dialkyl complexes

A series of novel chiral nonmetallocene pincer-type rare-earth metal dialkyl complexes bearing the chiral monoanionic tridentate C₂-symmetric 1,3-bis(oxazolinymethylidene)isoindoline (BOXMI-H) ligand (BOXMI)Ln(CH₂SiMe₃)₂ 1-3 (1: Ln = Sc, yield = 57%; 2: Ln = Lu, yield = 55%; 3: Ln = Y, yield = 62%) have been prepared in moderate yields via the acid-base reaction between the BOXMI ligand and rare-earth metal tri(trimethylsilylmethyl) complexes. The X-ray diffractions show that both of the complexes 1 and 2 contain one BOXMI ligand and two trimethylsilylmethyl ligands, adopting a distorted trigonal bipyramidal configuration. In the presence of a cocatalyst such as borate and AlR₃, these complexes 1-3 exhibit high activities of up to 6.8 × 10⁴ (g of polymer)/(mol_Ln h) and high cis-1,4 selectivities of up to 97% in the polymerization of isoprene in toluene, yielding the cis-1,4-polyisoprenes with heavy molecular weights (M_n of up to 710,000 g/mol) and bimodal molecular weight distributions (M_w/M_n = 2.0-4.5).