Characterizing membrane fouling formation during ultrafiltration of high-salinity organic wastewater

High-salinity organic wastewater usually consists of diverse highly concentrated ions such as Na⁺, Ca²⁺ and Al³⁺ etc., which may significantly influence the fouling propensity when membrane technique is employed for contaminants removal. The current work investigated the effects of high salinity especially high-concentration Na⁺, Ca²⁺ and Al³⁺ on UF fouling characteristics, where 2 M Na⁺ and 0.5–1.0 M Ca²⁺ or Al³⁺ were applied according to the general composition of high-salinity wastewater. The results demonstrated that the presence of high-concentration Na⁺ alone benefited the ultrafiltration of bovine serum albumin (BSA) solution, but posed adverse effects on the ultrafiltration of humic acid (HA) solution. Further addition of Ca²⁺ or Al³⁺ on the basis of Na⁺ was found to aggravate the development of BSA fouling. Such differentiated behaviors were further elucidated by the comprehensive fouling characterizations in terms of foulant properties, specific resistances, filtration modelling and fouling layer observations. Correlation analysis suggested that irreversible fouling had strong relationship with Al³⁺ addition, while reversible fouling seemed to be primarily influenced by foulant size. Meanwhile, membrane rejection in the presence of various salts remarkably decreased, which was negatively correlated with zeta potential. Consequently, this study should shed light on the membrane fouling formation for treating high-salinity organic wastewater using membrane techniques.