Bis(diethylenetriamine-κ3N)nickel hexafluorogermanate

Hong Xia Zhang; Guo Yu Yang; Yan Qiong Sun

doi:10.1107/S1600536803006160

Bis(diethylenetriamine-κ³N)nickel hexafluorogermanate

Hong Xia Zhang, Guo Yu Yang^*, Yan Qiong Sun

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The title compound, [Ni(dien)₂][GeF₆] (dien is diethylenetriamine, C₄H₁₃N₃), synthesized under mild solvothermal conditions, is a novel zero-dimensional material in which [GeF₆]^2- building anions are connected to [Ni(dien) ₂]²⁺ cations via hydrogen bonds between F atoms and N-H groups. Both metal atoms are located on special positions of site symmetry 2/m. Furthermore, one F and one N atom (including the attached H atom) are located on a mirror plane.

Original language	English
Pages (from-to)	m185-m187
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	4
DOIs	https://doi.org/10.1107/S1600536803006160
Publication status	Published - Apr 2003
Externally published	Yes

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title = "Bis(diethylenetriamine-κ3N)nickel hexafluorogermanate",

abstract = "The title compound, [Ni(dien)2][GeF6] (dien is diethylenetriamine, C4H13N3), synthesized under mild solvothermal conditions, is a novel zero-dimensional material in which [GeF6]2- building anions are connected to [Ni(dien) 2]2+ cations via hydrogen bonds between F atoms and N-H groups. Both metal atoms are located on special positions of site symmetry 2/m. Furthermore, one F and one N atom (including the attached H atom) are located on a mirror plane.",

author = "Zhang, {Hong Xia} and Yang, {Guo Yu} and Sun, {Yan Qiong}",

year = "2003",

month = apr,

doi = "10.1107/S1600536803006160",

language = "English",

volume = "59",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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T1 - Bis(diethylenetriamine-κ3N)nickel hexafluorogermanate

AU - Zhang, Hong Xia

AU - Yang, Guo Yu

AU - Sun, Yan Qiong

PY - 2003/4

Y1 - 2003/4

N2 - The title compound, [Ni(dien)2][GeF6] (dien is diethylenetriamine, C4H13N3), synthesized under mild solvothermal conditions, is a novel zero-dimensional material in which [GeF6]2- building anions are connected to [Ni(dien) 2]2+ cations via hydrogen bonds between F atoms and N-H groups. Both metal atoms are located on special positions of site symmetry 2/m. Furthermore, one F and one N atom (including the attached H atom) are located on a mirror plane.

AB - The title compound, [Ni(dien)2][GeF6] (dien is diethylenetriamine, C4H13N3), synthesized under mild solvothermal conditions, is a novel zero-dimensional material in which [GeF6]2- building anions are connected to [Ni(dien) 2]2+ cations via hydrogen bonds between F atoms and N-H groups. Both metal atoms are located on special positions of site symmetry 2/m. Furthermore, one F and one N atom (including the attached H atom) are located on a mirror plane.

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U2 - 10.1107/S1600536803006160

DO - 10.1107/S1600536803006160

M3 - Article

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JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

Bis(diethylenetriamine-κ³N)nickel hexafluorogermanate

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