Ba3M2[B3O6(OH)] 2[B4O7(OH)2] (M=Al, Ga): Two novel uv nonlinear optical metal borates containing two types of oxoboron clusters

Lin Cheng; Qi Wei; Han Qing Wu; Liu Jiang Zhou; Guo Yu Yang

doi:10.1002/chem.201303088

Ba₃M₂[B₃O₆(OH)] ₂[B₄O₇(OH)₂] (M=Al, Ga): Two novel uv nonlinear optical metal borates containing two types of oxoboron clusters

Lin Cheng, Qi Wei, Han Qing Wu, Liu Jiang Zhou, Guo Yu Yang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

108 Citations (Scopus)

Abstract

Two acentric metal borates Ba₃M₂- [B ₃O₆(OH)]₂[B₄O₇(OH) ₂] (M=Al, Ga) have been made under hydrothermal conditions; the MO₄ groups and two types of oxoboron cluster units interconnect to form a 3D porous layer with 9-/14-membered-ring intersecting channels (see figure), showing a good second harmonic generation effect of about three times that of KH₂PO₄ (KDP).

Original language	English
Pages (from-to)	17662-17667
Number of pages	6
Journal	Chemistry - A European Journal
Volume	19
Issue number	52
DOIs	https://doi.org/10.1002/chem.201303088
Publication status	Published - 23 Dec 2013
Externally published	Yes

Keywords

aluminum
boron
cluster compounds
gallium
nonlinear optics
oxygen

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10.1002/chem.201303088

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title = "Ba3M2[B3O6(OH)] 2[B4O7(OH)2] (M=Al, Ga): Two novel uv nonlinear optical metal borates containing two types of oxoboron clusters",

abstract = "Two acentric metal borates Ba3M2- [B 3O6(OH)]2[B4O7(OH) 2] (M=Al, Ga) have been made under hydrothermal conditions; the MO4 groups and two types of oxoboron cluster units interconnect to form a 3D porous layer with 9-/14-membered-ring intersecting channels (see figure), showing a good second harmonic generation effect of about three times that of KH2PO4 (KDP).",

keywords = "aluminum, boron, cluster compounds, gallium, nonlinear optics, oxygen",

author = "Lin Cheng and Qi Wei and Wu, {Han Qing} and Zhou, {Liu Jiang} and Yang, {Guo Yu}",

year = "2013",

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doi = "10.1002/chem.201303088",

language = "English",

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T1 - Ba3M2[B3O6(OH)] 2[B4O7(OH)2] (M=Al, Ga)

T2 - Two novel uv nonlinear optical metal borates containing two types of oxoboron clusters

AU - Cheng, Lin

AU - Wei, Qi

AU - Wu, Han Qing

AU - Zhou, Liu Jiang

AU - Yang, Guo Yu

PY - 2013/12/23

Y1 - 2013/12/23

N2 - Two acentric metal borates Ba3M2- [B 3O6(OH)]2[B4O7(OH) 2] (M=Al, Ga) have been made under hydrothermal conditions; the MO4 groups and two types of oxoboron cluster units interconnect to form a 3D porous layer with 9-/14-membered-ring intersecting channels (see figure), showing a good second harmonic generation effect of about three times that of KH2PO4 (KDP).

AB - Two acentric metal borates Ba3M2- [B 3O6(OH)]2[B4O7(OH) 2] (M=Al, Ga) have been made under hydrothermal conditions; the MO4 groups and two types of oxoboron cluster units interconnect to form a 3D porous layer with 9-/14-membered-ring intersecting channels (see figure), showing a good second harmonic generation effect of about three times that of KH2PO4 (KDP).

KW - aluminum

KW - boron

KW - cluster compounds

KW - gallium

KW - nonlinear optics

KW - oxygen

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SN - 0947-6539

VL - 19

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EP - 17667

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 52

ER -

Ba₃M₂[B₃O₆(OH)] ₂[B₄O₇(OH)₂] (M=Al, Ga): Two novel uv nonlinear optical metal borates containing two types of oxoboron clusters

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