Atomic Fe & FeP nanoparticles synergistically facilitate oxygen reduction reaction of hollow carbon hybrids

Wenxiu Yang, Xiangjian Liu, Huan Lv, Jianbo Jia*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

19 Citations (Scopus)

Abstract

Exploring highly active non-noble metal oxygen reduction reaction (ORR) catalysts and understanding the mechanism are very essential for future energy conversion and storage devices. Herein, we provide a novel method to produce FeP nanoparticles and single atom Fe co-doped porous hollow carbon hybrids (FeP@SA-Fe/HC) from iron metal–organic framework (NH2-MIL(Fe)), phytic acid and melamine. Interestingly, thanks for the co-existence of the atomic Fe and FeP nanoparticles, porous hollow microstructure, and heteroatom doping, the obtained FeP@SA-Fe/HC-900 hybrid shows very high ORR activity with a more positive half-wave potential of 0.843 V (vs. reversible hydrogen electrode) in 0.10 M KOH, comparing with the commercial 20 wt% Pt/C catalyst (0.807 V). Our methodology puts forwards a new sight to enhance the electrochemical catalytic performance of carbon composite materials through the synergistic effect of the atomic-metal and metal nanoparticles.

Original languageEnglish
Pages (from-to)371-375
Number of pages5
JournalJournal of Colloid and Interface Science
Volume583
DOIs
Publication statusPublished - 1 Feb 2021

Keywords

  • Hollow carbon
  • Iron phosphide nanoparticles
  • Oxygen reduction reaction
  • Single atom
  • Synergistic catalysis

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