Application of P (BAMO-r-AMMO) in propellant

Chi Zhang; Xiang Fei Zhang; Bin Zhai; Jie Li; Yun Jun Luo

Application of P (BAMO-r-AMMO) in propellant

Chi Zhang^*, Xiang Fei Zhang, Bin Zhai, Jie Li, Yun Jun Luo

^*Corresponding author for this work

School of Material Science and Engineering

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The composite propellant with a solid content of 80% was prepared by using 3, 3'-bisazidomethyloxetane-3-azidomethyl-3'-methyloxetane (P (BAMO-r-AMMO)) random copolymer as the prepolymer. The minimum free energy method was used to calculate the energy of formulation for the propellant. The density, heat of detonation, T_g and mechanical properties were measured by interfacial tension meter, oxygen bomb calorimeter, DSC and static tensile test. The results show that its standard theoretical specific impulse reaches 275.43 s (10MPa), density is 1.7924 g/cm³ and heat of detonation is 6124 kJ/kg, T_g is -50.80°C, tensile strength is 1.24 MPa and breaking elongation is 21%, which are higher than that of hydroxyl-terminated polybutadiene (HTPB) based and glycidyl azide polymer (GAP) based composite propellant under the same formulation, having more excellent comprehensive performance than HTPB based and GAP based composite propellant.

Original language	English
Pages (from-to)	61-64
Number of pages	4
Journal	Huozhayao Xuebao/Chinese Journal of Explosives and Propellants
Volume	36
Issue number	4
Publication status	Published - Aug 2013

Keywords

Energetic material
Material science
Mechanical properties
P (BAMO-r-AMMO)
Standard theoretical specific impulse
Thermoset composite propellant

Cite this

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title = "Application of P (BAMO-r-AMMO) in propellant",

abstract = "The composite propellant with a solid content of 80% was prepared by using 3, 3'-bisazidomethyloxetane-3-azidomethyl-3'-methyloxetane (P (BAMO-r-AMMO)) random copolymer as the prepolymer. The minimum free energy method was used to calculate the energy of formulation for the propellant. The density, heat of detonation, Tg and mechanical properties were measured by interfacial tension meter, oxygen bomb calorimeter, DSC and static tensile test. The results show that its standard theoretical specific impulse reaches 275.43 s (10MPa), density is 1.7924 g/cm3 and heat of detonation is 6124 kJ/kg, Tg is -50.80°C, tensile strength is 1.24 MPa and breaking elongation is 21%, which are higher than that of hydroxyl-terminated polybutadiene (HTPB) based and glycidyl azide polymer (GAP) based composite propellant under the same formulation, having more excellent comprehensive performance than HTPB based and GAP based composite propellant.",

keywords = "Energetic material, Material science, Mechanical properties, P (BAMO-r-AMMO), Standard theoretical specific impulse, Thermoset composite propellant",

author = "Chi Zhang and Zhang, {Xiang Fei} and Bin Zhai and Jie Li and Luo, {Yun Jun}",

year = "2013",

month = aug,

language = "English",

volume = "36",

pages = "61--64",

journal = "Huozhayao Xuebao/Chinese Journal of Explosives and Propellants",

issn = "1007-7812",

publisher = "China Ordnance Industry Corporation",

number = "4",

}

TY - JOUR

T1 - Application of P (BAMO-r-AMMO) in propellant

AU - Zhang, Chi

AU - Zhang, Xiang Fei

AU - Zhai, Bin

AU - Li, Jie

AU - Luo, Yun Jun

PY - 2013/8

Y1 - 2013/8

N2 - The composite propellant with a solid content of 80% was prepared by using 3, 3'-bisazidomethyloxetane-3-azidomethyl-3'-methyloxetane (P (BAMO-r-AMMO)) random copolymer as the prepolymer. The minimum free energy method was used to calculate the energy of formulation for the propellant. The density, heat of detonation, Tg and mechanical properties were measured by interfacial tension meter, oxygen bomb calorimeter, DSC and static tensile test. The results show that its standard theoretical specific impulse reaches 275.43 s (10MPa), density is 1.7924 g/cm3 and heat of detonation is 6124 kJ/kg, Tg is -50.80°C, tensile strength is 1.24 MPa and breaking elongation is 21%, which are higher than that of hydroxyl-terminated polybutadiene (HTPB) based and glycidyl azide polymer (GAP) based composite propellant under the same formulation, having more excellent comprehensive performance than HTPB based and GAP based composite propellant.

AB - The composite propellant with a solid content of 80% was prepared by using 3, 3'-bisazidomethyloxetane-3-azidomethyl-3'-methyloxetane (P (BAMO-r-AMMO)) random copolymer as the prepolymer. The minimum free energy method was used to calculate the energy of formulation for the propellant. The density, heat of detonation, Tg and mechanical properties were measured by interfacial tension meter, oxygen bomb calorimeter, DSC and static tensile test. The results show that its standard theoretical specific impulse reaches 275.43 s (10MPa), density is 1.7924 g/cm3 and heat of detonation is 6124 kJ/kg, Tg is -50.80°C, tensile strength is 1.24 MPa and breaking elongation is 21%, which are higher than that of hydroxyl-terminated polybutadiene (HTPB) based and glycidyl azide polymer (GAP) based composite propellant under the same formulation, having more excellent comprehensive performance than HTPB based and GAP based composite propellant.

KW - Energetic material

KW - Material science

KW - Mechanical properties

KW - P (BAMO-r-AMMO)

KW - Standard theoretical specific impulse

KW - Thermoset composite propellant

UR - http://www.scopus.com/inward/record.url?scp=84890812527&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:84890812527

SN - 1007-7812

VL - 36

SP - 61

EP - 64

JO - Huozhayao Xuebao/Chinese Journal of Explosives and Propellants

JF - Huozhayao Xuebao/Chinese Journal of Explosives and Propellants

IS - 4

ER -

Application of P (BAMO-r-AMMO) in propellant

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Keywords

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