An efficient catalytic method for the borohydride reaction of esters using diethylzinc as precatalyst

Congjian Ni; Hailong Yu; Ling Liu; Ben Yan; Bingyi Zhang; Xiaoli Ma; Xiuhui Zhang; Zhi Yang

doi:10.1039/d2nj03136a

An efficient catalytic method for the borohydride reaction of esters using diethylzinc as precatalyst

Congjian Ni, Hailong Yu, Ling Liu, Ben Yan, Bingyi Zhang, Xiaoli Ma^*, Xiuhui Zhang, Zhi Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

A cheap and easily available ZnEt₂ is an effective precatalyst, which can be used for the hydroboration reaction of various organic carbonates and esters with HBpin. The preliminary hydroboration reaction mechanism has been investigated via the corresponding DFT calculation.

Original language	English
Pages (from-to)	14635-14641
Number of pages	7
Journal	New Journal of Chemistry
Volume	46
Issue number	30
DOIs	https://doi.org/10.1039/d2nj03136a
Publication status	Published - 13 Jul 2022

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title = "An efficient catalytic method for the borohydride reaction of esters using diethylzinc as precatalyst",

abstract = "A cheap and easily available ZnEt2 is an effective precatalyst, which can be used for the hydroboration reaction of various organic carbonates and esters with HBpin. The preliminary hydroboration reaction mechanism has been investigated via the corresponding DFT calculation.",

author = "Congjian Ni and Hailong Yu and Ling Liu and Ben Yan and Bingyi Zhang and Xiaoli Ma and Xiuhui Zhang and Zhi Yang",

note = "Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry.",

year = "2022",

month = jul,

day = "13",

doi = "10.1039/d2nj03136a",

language = "English",

volume = "46",

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T1 - An efficient catalytic method for the borohydride reaction of esters using diethylzinc as precatalyst

AU - Ni, Congjian

AU - Yu, Hailong

AU - Liu, Ling

AU - Yan, Ben

AU - Zhang, Bingyi

AU - Ma, Xiaoli

AU - Zhang, Xiuhui

AU - Yang, Zhi

PY - 2022/7/13

Y1 - 2022/7/13

N2 - A cheap and easily available ZnEt2 is an effective precatalyst, which can be used for the hydroboration reaction of various organic carbonates and esters with HBpin. The preliminary hydroboration reaction mechanism has been investigated via the corresponding DFT calculation.

AB - A cheap and easily available ZnEt2 is an effective precatalyst, which can be used for the hydroboration reaction of various organic carbonates and esters with HBpin. The preliminary hydroboration reaction mechanism has been investigated via the corresponding DFT calculation.

UR - http://www.scopus.com/inward/record.url?scp=85134619385&partnerID=8YFLogxK

U2 - 10.1039/d2nj03136a

DO - 10.1039/d2nj03136a

M3 - Article

AN - SCOPUS:85134619385

SN - 1144-0546

VL - 46

SP - 14635

EP - 14641

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 30

ER -

An efficient catalytic method for the borohydride reaction of esters using diethylzinc as precatalyst

Abstract

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