An effective retro-cycloaddition of M3N@C80 (M = Sc, Lu, Ho) metallofulleropyrrolidines

Bo Wu; Taishan Wang; Zhuxia Zhang; Yongqiang Feng; Lihua Gan; Jiang Li; Chunru Wang

doi:10.1039/c3cc46247a

An effective retro-cycloaddition of M₃N@C₈₀ (M = Sc, Lu, Ho) metallofulleropyrrolidines

Bo Wu, Taishan Wang, Zhuxia Zhang, Yongqiang Feng, Lihua Gan, Jiang Li, Chunru Wang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Sc₃N@C₈₀ fulleropyrrolidines are typical metallofullerene derivatives which were generated by the reaction of Sc₃N@C₈₀ with N-trityloxazolidinone. Here we report an effective retro-reaction of Sc₃N@C₈₀ fulleropyrrolidine by using 3-chloroperoxybenzoic acid to give pristine Sc₃N@C₈₀ in a high yield. This technique is expected to be used for separating metallofullerenes (M₃N@C₈₀) from hollow fullerenes without HPLC.

Original language	English
Pages (from-to)	10489-10491
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	89
DOIs	https://doi.org/10.1039/c3cc46247a
Publication status	Published - 15 Oct 2013
Externally published	Yes

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title = "An effective retro-cycloaddition of M3N@C80 (M = Sc, Lu, Ho) metallofulleropyrrolidines",

abstract = "Sc3N@C80 fulleropyrrolidines are typical metallofullerene derivatives which were generated by the reaction of Sc3N@C80 with N-trityloxazolidinone. Here we report an effective retro-reaction of Sc3N@C80 fulleropyrrolidine by using 3-chloroperoxybenzoic acid to give pristine Sc3N@C80 in a high yield. This technique is expected to be used for separating metallofullerenes (M3N@C80) from hollow fullerenes without HPLC.",

author = "Bo Wu and Taishan Wang and Zhuxia Zhang and Yongqiang Feng and Lihua Gan and Jiang Li and Chunru Wang",

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T1 - An effective retro-cycloaddition of M3N@C80 (M = Sc, Lu, Ho) metallofulleropyrrolidines

AU - Wu, Bo

AU - Wang, Taishan

AU - Zhang, Zhuxia

AU - Feng, Yongqiang

AU - Gan, Lihua

AU - Li, Jiang

AU - Wang, Chunru

PY - 2013/10/15

Y1 - 2013/10/15

N2 - Sc3N@C80 fulleropyrrolidines are typical metallofullerene derivatives which were generated by the reaction of Sc3N@C80 with N-trityloxazolidinone. Here we report an effective retro-reaction of Sc3N@C80 fulleropyrrolidine by using 3-chloroperoxybenzoic acid to give pristine Sc3N@C80 in a high yield. This technique is expected to be used for separating metallofullerenes (M3N@C80) from hollow fullerenes without HPLC.

AB - Sc3N@C80 fulleropyrrolidines are typical metallofullerene derivatives which were generated by the reaction of Sc3N@C80 with N-trityloxazolidinone. Here we report an effective retro-reaction of Sc3N@C80 fulleropyrrolidine by using 3-chloroperoxybenzoic acid to give pristine Sc3N@C80 in a high yield. This technique is expected to be used for separating metallofullerenes (M3N@C80) from hollow fullerenes without HPLC.

UR - http://www.scopus.com/inward/record.url?scp=84885599748&partnerID=8YFLogxK

U2 - 10.1039/c3cc46247a

DO - 10.1039/c3cc46247a

M3 - Article

AN - SCOPUS:84885599748

SN - 1359-7345

VL - 49

SP - 10489

EP - 10491

JO - Chemical Communications

JF - Chemical Communications

IS - 89

ER -

An effective retro-cycloaddition of M₃N@C₈₀ (M = Sc, Lu, Ho) metallofulleropyrrolidines

Abstract

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