Abstract
Sc3N@C80 fulleropyrrolidines are typical metallofullerene derivatives which were generated by the reaction of Sc3N@C80 with N-trityloxazolidinone. Here we report an effective retro-reaction of Sc3N@C80 fulleropyrrolidine by using 3-chloroperoxybenzoic acid to give pristine Sc3N@C80 in a high yield. This technique is expected to be used for separating metallofullerenes (M3N@C80) from hollow fullerenes without HPLC.
Original language | English |
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Pages (from-to) | 10489-10491 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 49 |
Issue number | 89 |
DOIs | |
Publication status | Published - 15 Oct 2013 |
Externally published | Yes |