An Azide-Bridged Homospin Single-Chain Magnet: [Co(2,2′ -bithiazoline)(N3)2]n

Tian Fu Liu; Dan Fu; Song Gao; Yuan Zhu Zhang; Hao Ling Sun; Gang Su; Yong Jiang Liu

doi:10.1021/ja0380751

An Azide-Bridged Homospin Single-Chain Magnet: [Co(2,2′ -bithiazoline)(N₃)₂]_n

Tian Fu Liu, Dan Fu, Song Gao^*, Yuan Zhu Zhang, Hao Ling Sun, Gang Su, Yong Jiang Liu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

508 Citations (Scopus)

Abstract

A novel end-on azide-bridged homospin 1D chain, Co(bt)(N₃)₂ (1) (bt = 2,2′-bithiazoline), is constructed by sharing edges of Co(II) distorted octahedrons to form a helix, which shows magnetic hysteresis with steps and slow relaxation below 5?6 K, typical of single-chain magnet behavior.

Original language	English
Pages (from-to)	13976-13977
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	125
Issue number	46
DOIs	https://doi.org/10.1021/ja0380751
Publication status	Published - 19 Nov 2003
Externally published	Yes

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Liu, T. F., Fu, D., Gao, S., Zhang, Y. Z., Sun, H. L., Su, G., & Liu, Y. J. (2003). An Azide-Bridged Homospin Single-Chain Magnet: [Co(2,2′ -bithiazoline)(N₃)₂]_n. Journal of the American Chemical Society, 125(46), 13976-13977. https://doi.org/10.1021/ja0380751

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abstract = "A novel end-on azide-bridged homospin 1D chain, Co(bt)(N3)2 (1) (bt = 2,2′-bithiazoline), is constructed by sharing edges of Co(II) distorted octahedrons to form a helix, which shows magnetic hysteresis with steps and slow relaxation below 5?6 K, typical of single-chain magnet behavior.",

author = "Liu, {Tian Fu} and Dan Fu and Song Gao and Zhang, {Yuan Zhu} and Sun, {Hao Ling} and Gang Su and Liu, {Yong Jiang}",

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T2 - [Co(2,2′ -bithiazoline)(N3)2]n

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AU - Fu, Dan

AU - Gao, Song

AU - Zhang, Yuan Zhu

AU - Sun, Hao Ling

AU - Su, Gang

AU - Liu, Yong Jiang

PY - 2003/11/19

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AB - A novel end-on azide-bridged homospin 1D chain, Co(bt)(N3)2 (1) (bt = 2,2′-bithiazoline), is constructed by sharing edges of Co(II) distorted octahedrons to form a helix, which shows magnetic hysteresis with steps and slow relaxation below 5?6 K, typical of single-chain magnet behavior.

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An Azide-Bridged Homospin Single-Chain Magnet: [Co(2,2′ -bithiazoline)(N₃)₂]_n

Abstract

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