An alkali metal - Crown ether complex supported by a Keggin anion through the three terminal oxygen atoms in a single M3O13 triplet: Synthesis and characterization of [{Na(dibenzo-18-crown-6)(MeCN)}3{PMo12O40}]

W. You; E. Wang; Y. Xu; Y. Li; L. Xu; C. Hu

doi:10.1021/ic0012874

An alkali metal - Crown ether complex supported by a Keggin anion through the three terminal oxygen atoms in a single M₃O₁₃ triplet: Synthesis and characterization of [{Na(dibenzo-18-crown-6)(MeCN)}₃{PMo₁₂O₄₀}]

W. You, E. Wang^*, Y. Xu, Y. Li, L. Xu, C. Hu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

106 Citations (Scopus)

Abstract

An alkali metal complex supported by a Keggin unit, [{Na(dibenzo-18-crown-6)(MeCN)}₃{PMo₁₂O ₄₀}]], is synthesized and characterized by elemental analysis, IR and ¹H NMR spectra, and X-ray crystallography, showing that the α-Keggin [PMo₁₂O₄₀]^3- anion is coordinated to three [Na(dibenzo-18-crown-6)(MeCN)]⁺ units by using the three terminal oxygen atoms in a single M₃O₁₃ triplet.

Original language	English
Pages (from-to)	5468-5471
Number of pages	4
Journal	Inorganic Chemistry
Volume	40
Issue number	21
DOIs	https://doi.org/10.1021/ic0012874
Publication status	Published - 8 Oct 2001
Externally published	Yes

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@article{74afa433d92742f79be3ec5a237ccc97,

title = "An alkali metal - Crown ether complex supported by a Keggin anion through the three terminal oxygen atoms in a single M3O13 triplet: Synthesis and characterization of [{Na(dibenzo-18-crown-6)(MeCN)}3{PMo12O40}]",

abstract = "An alkali metal complex supported by a Keggin unit, [{Na(dibenzo-18-crown-6)(MeCN)}3{PMo12O 40}]], is synthesized and characterized by elemental analysis, IR and 1H NMR spectra, and X-ray crystallography, showing that the α-Keggin [PMo12O40]3- anion is coordinated to three [Na(dibenzo-18-crown-6)(MeCN)]+ units by using the three terminal oxygen atoms in a single M3O13 triplet.",

author = "W. You and E. Wang and Y. Xu and Y. Li and L. Xu and C. Hu",

year = "2001",

month = oct,

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doi = "10.1021/ic0012874",

language = "English",

volume = "40",

pages = "5468--5471",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "21",

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An alkali metal - Crown ether complex supported by a Keggin anion through the three terminal oxygen atoms in a single M₃O₁₃ triplet: Synthesis and characterization of [{Na(dibenzo-18-crown-6)(MeCN)}₃{PMo₁₂O₄₀}]. / You, W.; Wang, E.; Xu, Y. et al.
In: Inorganic Chemistry, Vol. 40, No. 21, 08.10.2001, p. 5468-5471.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - An alkali metal - Crown ether complex supported by a Keggin anion through the three terminal oxygen atoms in a single M3O13 triplet

T2 - Synthesis and characterization of [{Na(dibenzo-18-crown-6)(MeCN)}3{PMo12O40}]

AU - You, W.

AU - Wang, E.

AU - Xu, Y.

AU - Li, Y.

AU - Xu, L.

AU - Hu, C.

PY - 2001/10/8

Y1 - 2001/10/8

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AB - An alkali metal complex supported by a Keggin unit, [{Na(dibenzo-18-crown-6)(MeCN)}3{PMo12O 40}]], is synthesized and characterized by elemental analysis, IR and 1H NMR spectra, and X-ray crystallography, showing that the α-Keggin [PMo12O40]3- anion is coordinated to three [Na(dibenzo-18-crown-6)(MeCN)]+ units by using the three terminal oxygen atoms in a single M3O13 triplet.

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