An alkali metal - Crown ether complex supported by a Keggin anion through the three terminal oxygen atoms in a single M3O13 triplet: Synthesis and characterization of [{Na(dibenzo-18-crown-6)(MeCN)}3{PMo12O40}]

W. You; E. Wang; Y. Xu; Y. Li; L. Xu; C. Hu

doi:10.1021/ic0012874

An alkali metal - Crown ether complex supported by a Keggin anion through the three terminal oxygen atoms in a single M₃O₁₃ triplet: Synthesis and characterization of [{Na(dibenzo-18-crown-6)(MeCN)}₃{PMo₁₂O₄₀}]

W. You, E. Wang^*, Y. Xu, Y. Li, L. Xu, C. Hu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

107 Citations (Scopus)

Abstract

An alkali metal complex supported by a Keggin unit, [{Na(dibenzo-18-crown-6)(MeCN)}₃{PMo₁₂O ₄₀}]], is synthesized and characterized by elemental analysis, IR and ¹H NMR spectra, and X-ray crystallography, showing that the α-Keggin [PMo₁₂O₄₀]^3- anion is coordinated to three [Na(dibenzo-18-crown-6)(MeCN)]⁺ units by using the three terminal oxygen atoms in a single M₃O₁₃ triplet.

Original language	English
Pages (from-to)	5468-5471
Number of pages	4
Journal	Inorganic Chemistry
Volume	40
Issue number	21
DOIs	https://doi.org/10.1021/ic0012874
Publication status	Published - 8 Oct 2001
Externally published	Yes

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You, W., Wang, E., Xu, Y., Li, Y., Xu, L., & Hu, C. (2001). An alkali metal - Crown ether complex supported by a Keggin anion through the three terminal oxygen atoms in a single M₃O₁₃ triplet: Synthesis and characterization of [{Na(dibenzo-18-crown-6)(MeCN)}₃{PMo₁₂O₄₀}]. Inorganic Chemistry, 40(21), 5468-5471. https://doi.org/10.1021/ic0012874

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abstract = "An alkali metal complex supported by a Keggin unit, [{Na(dibenzo-18-crown-6)(MeCN)}3{PMo12O 40}]], is synthesized and characterized by elemental analysis, IR and 1H NMR spectra, and X-ray crystallography, showing that the α-Keggin [PMo12O40]3- anion is coordinated to three [Na(dibenzo-18-crown-6)(MeCN)]+ units by using the three terminal oxygen atoms in a single M3O13 triplet.",

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year = "2001",

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An alkali metal - Crown ether complex supported by a Keggin anion through the three terminal oxygen atoms in a single M₃O₁₃ triplet: Synthesis and characterization of [{Na(dibenzo-18-crown-6)(MeCN)}₃{PMo₁₂O₄₀}]. / You, W.; Wang, E.; Xu, Y. et al.
In: Inorganic Chemistry, Vol. 40, No. 21, 08.10.2001, p. 5468-5471.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - An alkali metal - Crown ether complex supported by a Keggin anion through the three terminal oxygen atoms in a single M3O13 triplet

T2 - Synthesis and characterization of [{Na(dibenzo-18-crown-6)(MeCN)}3{PMo12O40}]

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AU - Wang, E.

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AU - Li, Y.

AU - Xu, L.

AU - Hu, C.

PY - 2001/10/8

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AB - An alkali metal complex supported by a Keggin unit, [{Na(dibenzo-18-crown-6)(MeCN)}3{PMo12O 40}]], is synthesized and characterized by elemental analysis, IR and 1H NMR spectra, and X-ray crystallography, showing that the α-Keggin [PMo12O40]3- anion is coordinated to three [Na(dibenzo-18-crown-6)(MeCN)]+ units by using the three terminal oxygen atoms in a single M3O13 triplet.

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