A series of Ni6-substituted polyoxometalates derivated from tripodal alcohol ligands

Xin Xiong Li; Shou Tian Zheng; Wei Hui Fang; Guo Yu Yang

doi:10.1016/j.inoche.2011.06.020

A series of Ni₆-substituted polyoxometalates derivated from tripodal alcohol ligands

Xin Xiong Li, Shou Tian Zheng, Wei Hui Fang, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

A series of new polyoxometalates based on [Ni₆(μ₃- OH)₃(H₂O)₆(en)₃(B-α-PW ₉O₃₄)] (en = ethylenediamine) clusters capped by different tripodal alcohol ligands have been hydrothermally synthesized and characterized by IR, TGA and single-crystal X-ray diffraction, respectively. The experimental results indicate that the tripodal alcohol ligands can substitute three hydroxyl groups located on the axial positions of the Ni₆ cluster to form new polyoxometalates with different substituted modes.

Original language	English
Pages (from-to)	1541-1545
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	14
Issue number	9
DOIs	https://doi.org/10.1016/j.inoche.2011.06.020
Publication status	Published - Sept 2011

Keywords

Hydrothermal synthesis
Keggin
Nickel
Polyoxometalates
Tripodal alcohol ligand

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Li, X. X., Zheng, S. T., Fang, W. H., & Yang, G. Y. (2011). A series of Ni₆-substituted polyoxometalates derivated from tripodal alcohol ligands. Inorganic Chemistry Communications, 14(9), 1541-1545. https://doi.org/10.1016/j.inoche.2011.06.020

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title = "A series of Ni6-substituted polyoxometalates derivated from tripodal alcohol ligands",

abstract = "A series of new polyoxometalates based on [Ni6(μ3- OH)3(H2O)6(en)3(B-α-PW 9O34)] (en = ethylenediamine) clusters capped by different tripodal alcohol ligands have been hydrothermally synthesized and characterized by IR, TGA and single-crystal X-ray diffraction, respectively. The experimental results indicate that the tripodal alcohol ligands can substitute three hydroxyl groups located on the axial positions of the Ni6 cluster to form new polyoxometalates with different substituted modes.",

keywords = "Hydrothermal synthesis, Keggin, Nickel, Polyoxometalates, Tripodal alcohol ligand",

author = "Li, {Xin Xiong} and Zheng, {Shou Tian} and Fang, {Wei Hui} and Yang, {Guo Yu}",

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AU - Li, Xin Xiong

AU - Zheng, Shou Tian

AU - Fang, Wei Hui

AU - Yang, Guo Yu

PY - 2011/9

Y1 - 2011/9

N2 - A series of new polyoxometalates based on [Ni6(μ3- OH)3(H2O)6(en)3(B-α-PW 9O34)] (en = ethylenediamine) clusters capped by different tripodal alcohol ligands have been hydrothermally synthesized and characterized by IR, TGA and single-crystal X-ray diffraction, respectively. The experimental results indicate that the tripodal alcohol ligands can substitute three hydroxyl groups located on the axial positions of the Ni6 cluster to form new polyoxometalates with different substituted modes.

AB - A series of new polyoxometalates based on [Ni6(μ3- OH)3(H2O)6(en)3(B-α-PW 9O34)] (en = ethylenediamine) clusters capped by different tripodal alcohol ligands have been hydrothermally synthesized and characterized by IR, TGA and single-crystal X-ray diffraction, respectively. The experimental results indicate that the tripodal alcohol ligands can substitute three hydroxyl groups located on the axial positions of the Ni6 cluster to form new polyoxometalates with different substituted modes.

KW - Hydrothermal synthesis

KW - Keggin

KW - Nickel

KW - Polyoxometalates

KW - Tripodal alcohol ligand

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DO - 10.1016/j.inoche.2011.06.020

M3 - Article

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SN - 1387-7003

VL - 14

SP - 1541

EP - 1545

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 9

ER -

A series of Ni₆-substituted polyoxometalates derivated from tripodal alcohol ligands

Abstract

Keywords

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