A series of lanthanide germanate cluster organic frameworks

Lei Lei Li; Rui Pan; Jun Wei Zhao; Bai Feng Yang; Guo Yu Yang

doi:10.1039/c6dt01629d

A series of lanthanide germanate cluster organic frameworks

Lei Lei Li, Rui Pan, Jun Wei Zhao^*, Bai Feng Yang, Guo Yu Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Six new lanthanide (Ln) germanate cluster organic frameworks (LnGeCOFs) derived from {Ln₈Ge₁₂} cage cluster units {[Nd(pza)₂(H₂O)] [Nd₈Ge₁₂(μ₃-O)₂₄E₁₂(pza)(H₂O)₁₂]}·3H₂O (1), {[Dy(CH₃COO)(CO₃)(H₂O)]₂[Dy₈Ge₁₂(μ₃-O)₂₄E₁₂(H₂O)₁₂]}·11H₂O (2), {[TbGeE(HO)₂O(pza) (H₂O)]₂[Tb₈Ge₁₂(μ₃-O)₂₄E₁₂(H₂O)₆]}·18H₂O (3), {[DyGeE(HO)₂O(C₃H₅NO₂)(H₂O)]₂[Dy₈Ge₁₂(μ₃-O)₂₄E₁₂(H₂O)₈]}·8H₂O (4), {[Tb(PCA)₂ (H₂O)]₃[Tb₈Ge₁₂(μ₃-O)₂₄E₁₂(H₂O)₄]}·(OH)₃·10H₂O (5) and {[Dy(pza)₂(H₂O)][Dy(pza)₂(H₂O)₂][Dy(pza)₃(H₂O)][Dy₈Ge₁₂(μ₃-O)₂₄E₁₂(pza)(HCOO) (H₂O)₆]}·5H₂O (6) have been hydrothermally synthesized and structurally characterized. Increasing the amount of the second ligands can induce not only the assembly from 1 to 5, 6 based on Ln oxides as the starting sources, but also the assembly from 2 to 3, 4 based on Ln salts as the starting sources. The successful preparation of these LnGeCOFs suggests the importance of the second ligands in the structural construction of 1-6. To our knowledge, 1 is the first example that includes right- and left-handed helical chains among LnGeCOFs based on bis(carboxyethylgermanium)sesquioxide. 2, 4 and 6 are the first dysprosium incorporated organogermanates based on bis(carboxyethylgermanium)sesquioxide. 4 and 5 display very open framework structures with a solvent-accessible volume of 34.6% for 4 and 35.0% for 5. Moreover, the solid-state photoluminescence properties of 1, 3 and 5 have been investigated at room temperature and they exhibit the characteristic emission bands derived from Ln cations.

Original language	English
Pages (from-to)	11958-11967
Number of pages	10
Journal	Dalton Transactions
Volume	45
Issue number	30
DOIs	https://doi.org/10.1039/c6dt01629d
Publication status	Published - 2016

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@article{2b4e90b70e794a92b730cde7be4f497e,

title = "A series of lanthanide germanate cluster organic frameworks",

abstract = "Six new lanthanide (Ln) germanate cluster organic frameworks (LnGeCOFs) derived from {Ln8Ge12} cage cluster units {[Nd(pza)2(H2O)] [Nd8Ge12(μ3-O)24E12(pza)(H2O)12]}·3H2O (1), {[Dy(CH3COO)(CO3)(H2O)]2[Dy8Ge12(μ3-O)24E12(H2O)12]}·11H2O (2), {[TbGeE(HO)2O(pza) (H2O)]2[Tb8Ge12(μ3-O)24E12(H2O)6]}·18H2O (3), {[DyGeE(HO)2O(C3H5NO2)(H2O)]2[Dy8Ge12(μ3-O)24E12(H2O)8]}·8H2O (4), {[Tb(PCA)2 (H2O)]3[Tb8Ge12(μ3-O)24E12(H2O)4]}·(OH)3·10H2O (5) and {[Dy(pza)2(H2O)][Dy(pza)2(H2O)2][Dy(pza)3(H2O)][Dy8Ge12(μ3-O)24E12(pza)(HCOO) (H2O)6]}·5H2O (6) have been hydrothermally synthesized and structurally characterized. Increasing the amount of the second ligands can induce not only the assembly from 1 to 5, 6 based on Ln oxides as the starting sources, but also the assembly from 2 to 3, 4 based on Ln salts as the starting sources. The successful preparation of these LnGeCOFs suggests the importance of the second ligands in the structural construction of 1-6. To our knowledge, 1 is the first example that includes right- and left-handed helical chains among LnGeCOFs based on bis(carboxyethylgermanium)sesquioxide. 2, 4 and 6 are the first dysprosium incorporated organogermanates based on bis(carboxyethylgermanium)sesquioxide. 4 and 5 display very open framework structures with a solvent-accessible volume of 34.6% for 4 and 35.0% for 5. Moreover, the solid-state photoluminescence properties of 1, 3 and 5 have been investigated at room temperature and they exhibit the characteristic emission bands derived from Ln cations.",

author = "Li, {Lei Lei} and Rui Pan and Zhao, {Jun Wei} and Yang, {Bai Feng} and Yang, {Guo Yu}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",

year = "2016",

doi = "10.1039/c6dt01629d",

language = "English",

volume = "45",

pages = "11958--11967",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "30",

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TY - JOUR

T1 - A series of lanthanide germanate cluster organic frameworks

AU - Li, Lei Lei

AU - Pan, Rui

AU - Zhao, Jun Wei

AU - Yang, Bai Feng

AU - Yang, Guo Yu

PY - 2016

Y1 - 2016

N2 - Six new lanthanide (Ln) germanate cluster organic frameworks (LnGeCOFs) derived from {Ln8Ge12} cage cluster units {[Nd(pza)2(H2O)] [Nd8Ge12(μ3-O)24E12(pza)(H2O)12]}·3H2O (1), {[Dy(CH3COO)(CO3)(H2O)]2[Dy8Ge12(μ3-O)24E12(H2O)12]}·11H2O (2), {[TbGeE(HO)2O(pza) (H2O)]2[Tb8Ge12(μ3-O)24E12(H2O)6]}·18H2O (3), {[DyGeE(HO)2O(C3H5NO2)(H2O)]2[Dy8Ge12(μ3-O)24E12(H2O)8]}·8H2O (4), {[Tb(PCA)2 (H2O)]3[Tb8Ge12(μ3-O)24E12(H2O)4]}·(OH)3·10H2O (5) and {[Dy(pza)2(H2O)][Dy(pza)2(H2O)2][Dy(pza)3(H2O)][Dy8Ge12(μ3-O)24E12(pza)(HCOO) (H2O)6]}·5H2O (6) have been hydrothermally synthesized and structurally characterized. Increasing the amount of the second ligands can induce not only the assembly from 1 to 5, 6 based on Ln oxides as the starting sources, but also the assembly from 2 to 3, 4 based on Ln salts as the starting sources. The successful preparation of these LnGeCOFs suggests the importance of the second ligands in the structural construction of 1-6. To our knowledge, 1 is the first example that includes right- and left-handed helical chains among LnGeCOFs based on bis(carboxyethylgermanium)sesquioxide. 2, 4 and 6 are the first dysprosium incorporated organogermanates based on bis(carboxyethylgermanium)sesquioxide. 4 and 5 display very open framework structures with a solvent-accessible volume of 34.6% for 4 and 35.0% for 5. Moreover, the solid-state photoluminescence properties of 1, 3 and 5 have been investigated at room temperature and they exhibit the characteristic emission bands derived from Ln cations.

AB - Six new lanthanide (Ln) germanate cluster organic frameworks (LnGeCOFs) derived from {Ln8Ge12} cage cluster units {[Nd(pza)2(H2O)] [Nd8Ge12(μ3-O)24E12(pza)(H2O)12]}·3H2O (1), {[Dy(CH3COO)(CO3)(H2O)]2[Dy8Ge12(μ3-O)24E12(H2O)12]}·11H2O (2), {[TbGeE(HO)2O(pza) (H2O)]2[Tb8Ge12(μ3-O)24E12(H2O)6]}·18H2O (3), {[DyGeE(HO)2O(C3H5NO2)(H2O)]2[Dy8Ge12(μ3-O)24E12(H2O)8]}·8H2O (4), {[Tb(PCA)2 (H2O)]3[Tb8Ge12(μ3-O)24E12(H2O)4]}·(OH)3·10H2O (5) and {[Dy(pza)2(H2O)][Dy(pza)2(H2O)2][Dy(pza)3(H2O)][Dy8Ge12(μ3-O)24E12(pza)(HCOO) (H2O)6]}·5H2O (6) have been hydrothermally synthesized and structurally characterized. Increasing the amount of the second ligands can induce not only the assembly from 1 to 5, 6 based on Ln oxides as the starting sources, but also the assembly from 2 to 3, 4 based on Ln salts as the starting sources. The successful preparation of these LnGeCOFs suggests the importance of the second ligands in the structural construction of 1-6. To our knowledge, 1 is the first example that includes right- and left-handed helical chains among LnGeCOFs based on bis(carboxyethylgermanium)sesquioxide. 2, 4 and 6 are the first dysprosium incorporated organogermanates based on bis(carboxyethylgermanium)sesquioxide. 4 and 5 display very open framework structures with a solvent-accessible volume of 34.6% for 4 and 35.0% for 5. Moreover, the solid-state photoluminescence properties of 1, 3 and 5 have been investigated at room temperature and they exhibit the characteristic emission bands derived from Ln cations.

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U2 - 10.1039/c6dt01629d

DO - 10.1039/c6dt01629d

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AN - SCOPUS:84979918979

SN - 1477-9226

VL - 45

SP - 11958

EP - 11967

JO - Dalton Transactions

JF - Dalton Transactions

IS - 30

ER -

A series of lanthanide germanate cluster organic frameworks

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