Abstract
A novel metal-organic framework (MOF), the first 3D 1,3-thiazolidine-2-thione (tzdtH) coordinated MOF with strong Ag-Ag interaction (2.9001 Å) in tetranuclear silver clusters, was synthesized. The single-crystal X-ray diffraction shows that the versatile ligand tzdtH contributes greatly to the formation of the 3D framework and the helical structure.
Original language | English |
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Pages (from-to) | 1161-1164 |
Number of pages | 4 |
Journal | Inorganic Chemistry Communications |
Volume | 9 |
Issue number | 12 |
DOIs | |
Publication status | Published - Dec 2006 |
Keywords
- 1,3-Thiazolidine-2-thione
- Helical structure
- Single-crystal X-ray diffraction
- Strong Ag-Ag interaction
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Dive into the research topics of 'A novel 3D metal-organic framework with helical structure: Synthesis and structure of [Ag4(tzdt)4(μ-tzdtH)2]n (tzdtH=1,3-thiazolidine-2-thione)'. Together they form a unique fingerprint.Cite this
Wei, X. Y., Chu, W., Huang, R. D., Zhang, S. W., Li, H., & Zhu, Q. L. (2006). A novel 3D metal-organic framework with helical structure: Synthesis and structure of [Ag4(tzdt)4(μ-tzdtH)2]n (tzdtH=1,3-thiazolidine-2-thione). Inorganic Chemistry Communications, 9(12), 1161-1164. https://doi.org/10.1016/j.inoche.2006.07.021