Abstract
A new method for the synthesis of 4,4′,6,6′-tetra(azido)azo-1,3,5-triazine (TAAT) is described. The key intermediate 4,4′,6,6′-tetra(azido)hydrazo-1,3,5-triazine (TAHT) was synthesized by nucleophilic substitution in the case of sodium azide as nucleophile. N-Bromosuccinide (NBS) was used as oxidant to oxidize TAHT by a tractable operation under mild reaction condition. The target compound TAAT was obtained with a facile process and high overall yield of 81%. The structures of TAAT and its intermediates were identified by spectroscopic methods.
Original language | English |
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Pages (from-to) | 1037-1039 |
Number of pages | 3 |
Journal | Chinese Chemical Letters |
Volume | 18 |
Issue number | 9 |
DOIs | |
Publication status | Published - Sept 2007 |
Keywords
- Azide
- High-nitrogen compounds
- Synthesis
- Triazine
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Li, X. T., Li, S. H., Pang, S. P., Yu, Y. Z., & Luo, Y. J. (2007). A new efficient route for the synthesis of 4,4′,6,6′-tetra(azido)azo-1,3,5-triazine. Chinese Chemical Letters, 18(9), 1037-1039. https://doi.org/10.1016/j.cclet.2007.06.028