A highly stable octa-coordinated energetic complex

Wenchao Tong; Mei Bian; Yongan Feng; Tonglai Zhang; Shuangqi Hu; Li Yang

doi:10.1039/d0ce01008a

A highly stable octa-coordinated energetic complex

Wenchao Tong, Mei Bian, Yongan Feng, Tonglai Zhang, Shuangqi Hu, Li Yang^*

^*Corresponding author for this work

School of Mechatronical Engineering

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The quest for high-energy-density materials (HEDMs) based on transition metal complexes is focused on low-coordinate species. High-coordinate analogues are extremely rare. Here, the first example of a highly energetic complex (HEC) with the highest coordination number of eight in 3d metal coordination chemistry is reported. Its structure was confirmed by single crystal X-ray diffraction. Its remarkably high stability has also been investigated.

Original language	English
Pages (from-to)	6591-6595
Number of pages	5
Journal	CrystEngComm
Volume	22
Issue number	40
DOIs	https://doi.org/10.1039/d0ce01008a
Publication status	Published - 28 Oct 2020

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title = "A highly stable octa-coordinated energetic complex",

abstract = "The quest for high-energy-density materials (HEDMs) based on transition metal complexes is focused on low-coordinate species. High-coordinate analogues are extremely rare. Here, the first example of a highly energetic complex (HEC) with the highest coordination number of eight in 3d metal coordination chemistry is reported. Its structure was confirmed by single crystal X-ray diffraction. Its remarkably high stability has also been investigated.",

author = "Wenchao Tong and Mei Bian and Yongan Feng and Tonglai Zhang and Shuangqi Hu and Li Yang",

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T1 - A highly stable octa-coordinated energetic complex

AU - Tong, Wenchao

AU - Bian, Mei

AU - Feng, Yongan

AU - Zhang, Tonglai

AU - Hu, Shuangqi

AU - Yang, Li

PY - 2020/10/28

Y1 - 2020/10/28

N2 - The quest for high-energy-density materials (HEDMs) based on transition metal complexes is focused on low-coordinate species. High-coordinate analogues are extremely rare. Here, the first example of a highly energetic complex (HEC) with the highest coordination number of eight in 3d metal coordination chemistry is reported. Its structure was confirmed by single crystal X-ray diffraction. Its remarkably high stability has also been investigated.

AB - The quest for high-energy-density materials (HEDMs) based on transition metal complexes is focused on low-coordinate species. High-coordinate analogues are extremely rare. Here, the first example of a highly energetic complex (HEC) with the highest coordination number of eight in 3d metal coordination chemistry is reported. Its structure was confirmed by single crystal X-ray diffraction. Its remarkably high stability has also been investigated.

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DO - 10.1039/d0ce01008a

M3 - Article

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VL - 22

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JO - CrystEngComm

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ER -

A highly stable octa-coordinated energetic complex

Abstract

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