Xu, J., Tang, W., Yang, C., Manke, I., Chen, N., Lai, F., Xu, T., An, S., Liu, H., Zhang, Z., Cao, Y., Wang, N., Zhao, S., Niu, D., & Chen, R. (2021). A Highly Conductive COF@CNT Electrocatalyst Boosting Polysulfide Conversion for Li-S Chemistry. ACS Energy Letters, 6(9), 3053-3062. https://doi.org/10.1021/acsenergylett.1c00943
Xu, Jie ; Tang, Weiqiang ; Yang, Chao et al. / A Highly Conductive COF@CNT Electrocatalyst Boosting Polysulfide Conversion for Li-S Chemistry. In: ACS Energy Letters. 2021 ; Vol. 6, No. 9. pp. 3053-3062.
@article{215a77feb56541c1a77b37e6097c7fe4,
title = "A Highly Conductive COF@CNT Electrocatalyst Boosting Polysulfide Conversion for Li-S Chemistry",
abstract = "The catalysis of covalent organic frameworks (COFs) in Li-S chemistry is largely blocked by a weak chemical interaction and low conductivity. Herein, a new kind of diketopyrrolopyrrole (DPP)-based COF is in situ fabricated onto the carbon nanotube (CNT) surface (denoted as COF@CNT) to uncover the electrocatalysis behavior by its strong chemical interaction and highly conductive property. We declare that the electrocatalytic activity of DPP-COF can be maximized by introducing an appropriate content of CNT (66 wt \%); the analyses including density functional theory calculations, X-ray photoelectron spectroscopy, Fourier transform infrared, and Raman show that the DPP moiety can mediate the conversion of polysulfides contributed by a CO/C-O bonding conversion. Hence, the modified battery shows a 0.042\% decay rate over 1000 cycles and achieves a desirable capacity of 8.7 mAh cm-2 with 10 mg cm-2 sulfur loading and lean electrolyte (E/S = 5). This work will inspire the rational design of COF@support hybrids for various electrocatalysis applications.",
author = "Jie Xu and Weiqiang Tang and Chao Yang and Ingo Manke and Nan Chen and Feili Lai and Ting Xu and Shuhao An and Honglai Liu and Zhiliang Zhang and Yongjie Cao and Nan Wang and Shuangliang Zhao and Dongfang Niu and Renjie Chen",
note = "Publisher Copyright: {\textcopyright} 2021 American Chemical Society.",
year = "2021",
month = sep,
day = "10",
doi = "10.1021/acsenergylett.1c00943",
language = "English",
volume = "6",
pages = "3053--3062",
journal = "ACS Energy Letters",
issn = "2380-8195",
publisher = "American Chemical Society",
number = "9",
}
Xu, J, Tang, W, Yang, C, Manke, I, Chen, N, Lai, F, Xu, T, An, S, Liu, H, Zhang, Z, Cao, Y, Wang, N, Zhao, S, Niu, D & Chen, R 2021, 'A Highly Conductive COF@CNT Electrocatalyst Boosting Polysulfide Conversion for Li-S Chemistry', ACS Energy Letters, vol. 6, no. 9, pp. 3053-3062. https://doi.org/10.1021/acsenergylett.1c00943
A Highly Conductive COF@CNT Electrocatalyst Boosting Polysulfide Conversion for Li-S Chemistry. / Xu, Jie; Tang, Weiqiang; Yang, Chao et al.
In:
ACS Energy Letters, Vol. 6, No. 9, 10.09.2021, p. 3053-3062.
Research output: Contribution to journal › Article › peer-review
TY - JOUR
T1 - A Highly Conductive COF@CNT Electrocatalyst Boosting Polysulfide Conversion for Li-S Chemistry
AU - Xu, Jie
AU - Tang, Weiqiang
AU - Yang, Chao
AU - Manke, Ingo
AU - Chen, Nan
AU - Lai, Feili
AU - Xu, Ting
AU - An, Shuhao
AU - Liu, Honglai
AU - Zhang, Zhiliang
AU - Cao, Yongjie
AU - Wang, Nan
AU - Zhao, Shuangliang
AU - Niu, Dongfang
AU - Chen, Renjie
N1 - Publisher Copyright:
© 2021 American Chemical Society.
PY - 2021/9/10
Y1 - 2021/9/10
N2 - The catalysis of covalent organic frameworks (COFs) in Li-S chemistry is largely blocked by a weak chemical interaction and low conductivity. Herein, a new kind of diketopyrrolopyrrole (DPP)-based COF is in situ fabricated onto the carbon nanotube (CNT) surface (denoted as COF@CNT) to uncover the electrocatalysis behavior by its strong chemical interaction and highly conductive property. We declare that the electrocatalytic activity of DPP-COF can be maximized by introducing an appropriate content of CNT (66 wt %); the analyses including density functional theory calculations, X-ray photoelectron spectroscopy, Fourier transform infrared, and Raman show that the DPP moiety can mediate the conversion of polysulfides contributed by a CO/C-O bonding conversion. Hence, the modified battery shows a 0.042% decay rate over 1000 cycles and achieves a desirable capacity of 8.7 mAh cm-2 with 10 mg cm-2 sulfur loading and lean electrolyte (E/S = 5). This work will inspire the rational design of COF@support hybrids for various electrocatalysis applications.
AB - The catalysis of covalent organic frameworks (COFs) in Li-S chemistry is largely blocked by a weak chemical interaction and low conductivity. Herein, a new kind of diketopyrrolopyrrole (DPP)-based COF is in situ fabricated onto the carbon nanotube (CNT) surface (denoted as COF@CNT) to uncover the electrocatalysis behavior by its strong chemical interaction and highly conductive property. We declare that the electrocatalytic activity of DPP-COF can be maximized by introducing an appropriate content of CNT (66 wt %); the analyses including density functional theory calculations, X-ray photoelectron spectroscopy, Fourier transform infrared, and Raman show that the DPP moiety can mediate the conversion of polysulfides contributed by a CO/C-O bonding conversion. Hence, the modified battery shows a 0.042% decay rate over 1000 cycles and achieves a desirable capacity of 8.7 mAh cm-2 with 10 mg cm-2 sulfur loading and lean electrolyte (E/S = 5). This work will inspire the rational design of COF@support hybrids for various electrocatalysis applications.
UR - http://www.scopus.com/inward/record.url?scp=85114036595&partnerID=8YFLogxK
U2 - 10.1021/acsenergylett.1c00943
DO - 10.1021/acsenergylett.1c00943
M3 - Article
AN - SCOPUS:85114036595
SN - 2380-8195
VL - 6
SP - 3053
EP - 3062
JO - ACS Energy Letters
JF - ACS Energy Letters
IS - 9
ER -
Xu J, Tang W, Yang C, Manke I, Chen N, Lai F et al. A Highly Conductive COF@CNT Electrocatalyst Boosting Polysulfide Conversion for Li-S Chemistry. ACS Energy Letters. 2021 Sept 10;6(9):3053-3062. doi: 10.1021/acsenergylett.1c00943
