A dual pathway in the solid‐state photoreaction of nitrobenzaldehydes with indole

Ji‐Ben ‐B Meng; Da‐Ming ‐M Du; Guo‐Xiang ‐X Xiong; Wen‐Guang ‐G Wang; Yong‐Mei ‐M Wang; Hideko Koshima; Teruo Matsuura

doi:10.1002/jhet.5570310121

A dual pathway in the solid‐state photoreaction of nitrobenzaldehydes with indole

Ji‐Ben ‐B Meng, Da‐Ming ‐M Du, Guo‐Xiang ‐X Xiong, Wen‐Guang ‐G Wang, Yong‐Mei ‐M Wang, Hideko Koshima, Teruo Matsuura^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

The solid‐state photoreaction of the mixed crystals between nitrobenzaldehydes and indole was found to give nitrophenyl‐(bis‐3‐indolyl)methane (3) and nitrophenyl‐(3‐indolyl)methanol (4). The structure of the ortho isomer 4c was established by X‐ray crystallographic analysis. A dual pathway from an oxetane intermediate 5 is proposed for the formation of 3 and 4.

Original language	English
Pages (from-to)	121-124
Number of pages	4
Journal	Journal of Heterocyclic Chemistry
Volume	31
Issue number	1
DOIs	https://doi.org/10.1002/jhet.5570310121
Publication status	Published - 1994
Externally published	Yes

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Meng, JB. B., Du, DM. M., Xiong, GX. X., Wang, WG. G., Wang, YM. M., Koshima, H., & Matsuura, T. (1994). A dual pathway in the solid‐state photoreaction of nitrobenzaldehydes with indole. Journal of Heterocyclic Chemistry, 31(1), 121-124. https://doi.org/10.1002/jhet.5570310121

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abstract = "The solid‐state photoreaction of the mixed crystals between nitrobenzaldehydes and indole was found to give nitrophenyl‐(bis‐3‐indolyl)methane (3) and nitrophenyl‐(3‐indolyl)methanol (4). The structure of the ortho isomer 4c was established by X‐ray crystallographic analysis. A dual pathway from an oxetane intermediate 5 is proposed for the formation of 3 and 4.",

author = "Meng, {Ji‐Ben ‐B} and Du, {Da‐Ming ‐M} and Xiong, {Guo‐Xiang ‐X} and Wang, {Wen‐Guang ‐G} and Wang, {Yong‐Mei ‐M} and Hideko Koshima and Teruo Matsuura",

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doi = "10.1002/jhet.5570310121",

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T1 - A dual pathway in the solid‐state photoreaction of nitrobenzaldehydes with indole

AU - Meng, Ji‐Ben ‐B

AU - Du, Da‐Ming ‐M

AU - Xiong, Guo‐Xiang ‐X

AU - Wang, Wen‐Guang ‐G

AU - Wang, Yong‐Mei ‐M

AU - Koshima, Hideko

AU - Matsuura, Teruo

PY - 1994

Y1 - 1994

N2 - The solid‐state photoreaction of the mixed crystals between nitrobenzaldehydes and indole was found to give nitrophenyl‐(bis‐3‐indolyl)methane (3) and nitrophenyl‐(3‐indolyl)methanol (4). The structure of the ortho isomer 4c was established by X‐ray crystallographic analysis. A dual pathway from an oxetane intermediate 5 is proposed for the formation of 3 and 4.

AB - The solid‐state photoreaction of the mixed crystals between nitrobenzaldehydes and indole was found to give nitrophenyl‐(bis‐3‐indolyl)methane (3) and nitrophenyl‐(3‐indolyl)methanol (4). The structure of the ortho isomer 4c was established by X‐ray crystallographic analysis. A dual pathway from an oxetane intermediate 5 is proposed for the formation of 3 and 4.

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U2 - 10.1002/jhet.5570310121

DO - 10.1002/jhet.5570310121

M3 - Article

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VL - 31

SP - 121

EP - 124

JO - Journal of Heterocyclic Chemistry

JF - Journal of Heterocyclic Chemistry

IS - 1

ER -

A dual pathway in the solid‐state photoreaction of nitrobenzaldehydes with indole

Abstract

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