He has long been engaged in research on the reaction mechanism of gaseous atomic clusters catalytic conversion of inert small molecules (such as CO, CO2, NO, etc.). Small molecules abundant in nature are difficult to transform under mild conditions, but the related process is of great significance to the development of environment, energy and other fields. Cluster reaction research is highly dependent on advanced instruments and equipment, and designing and building scientific instruments from scratch is the premise of cluster research. We sincerely welcome aspiring young people who are interested in instrument design and construction to join our team.
I Am the first or corresponding author in Nat. Commun., J. am. Chem. Soc., Angew. Chem. Int. Ed., J. Phys. Chem. Lett. He has published more than 60 papers in other journals. As the person in charge of the National Natural Science Foundation of China (national Youth talent project, major research plan, surface project, etc. 5 projects) and the Beijing Municipal Fund and other projects; Was selected as a member of Chinese Academy of Sciences Youth Innovation Promotion Association, and was rated as an excellent member at the end of the exam; Participate in key R&D projects of the Ministry of Science and Technology as an important backbone; Presided over the youth innovation project and youth talent cultivation project of the Center of Excellence of the Chemical Institute. He was invited to serve on the editorial board of Chemical Bulletin, Applied Chemistry and Chinese Chemical Letters.
Experimental and theoretical research on cluster physics and chemistry, the main directions are:
1. Design and independent construction of cluster scientific experimental instruments
2. Study on the catalytic conversion mechanism of inert small molecules (such as CO, NO, CO2, etc.) on metal clusters
3. Controlled Preparation and Screening of magic number atomic Clusters
2007.09-2011.01 Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Doctor of Science
2004.09-2007.07 Master of Science, Jilin University
2000.09-2004.07 Jilin Normal University, Bachelor of Science
2023.08-present School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Professor
2019.11-2023.07 Institute of Chemistry, Chinese Academy of Sciences, Researcher
2013.07-2019.10 Associate Researcher, Institute of Chemistry, Chinese Academy of Sciences
2013.01-2013.06 Assistant Researcher, Institute of Chemistry, Chinese Academy of Sciences
2011.03-2012.12 Postdoctoral Fellow, Institute of Chemistry, Chinese Academy of Sciences
Host project:
1. National Key Research and Development Project, 2021YFA1500704, Rational design and experimental Verification of catalysts for efficient CO2 conversion, RMB 3 million, 2022.01-2026.12, important research backbone, in progress.
2. Major Research Plan Cultivation Project of the Foundation Committee, 92161116, Mechanism of CO dissociation and hydrogenation on heteronuclear metal Clusters, 750,000, 2022.01-2024.12, Host, in progress.
3. Outstanding Youth Science Fund Project of the Foundation Committee, 22022308, Catalytic Reaction Mechanism of heteronuclear metal Cluster Model, 1.2 million, 2021.01-2023.12, Host, in research.
4. Excellent Member Project of Youth Promotion Association of Chinese Academy of Sciences: Y202007, Catalytic reaction mechanism of heteronuclear metal Cluster Model, 500,000, 2021.01-2023.12, Host, in research.
5. The electronegativity Ladder Effect in the Reaction of neutral heteronuclear metal oxide clusters with CO, 21773254, 2018.01-2021.12, Host, Completed.
6. Surface Project of the Foundation Committee, 21573246, Study on the reaction of some important transition metal clusters with CO2, 680,000, 2016.01-2019.12, Host, completed.
7. Youth Fund Project of Foundation Committee, 21303215, Research on Catalytic oxidation of CO by typical Heteronuclear oxide clusters such as Gold-titanium, 250,000, 2014.01-2016.12, Host, completed.
8. Beijing Natural Science Foundation Project: 2172059, Activation and Transformation of Noble Metal monatom-doped oxide Clusters into inert small molecules, 200,000, 2017.01-2018.12, Host, completed.
9. Member of Youth Innovation Promotion Association, Chinese Academy of Sciences, 2016030, Activation and transformation of small molecules on metal clusters, 700,000, 2016.01-2019.12, Host, Completed.
10. Youth Innovation Project, Center of Excellence, Institute of Chemistry, Chinese Academy of Sciences, CO2 Hydrogenation and C-C Coupling Reaction, 1.5 million, 2017.05-2019.05, host, completed.
11. Young Talents Cultivation Project, Institute of Chemistry, Chinese Academy of Sciences, Activation and Transformation of inert Small molecules containing noble metal oxide Clusters, 200000, 2016.01-2017.12, host, completed.
12. The Fifth Batch of Special Grants from Postdoctoral Science Foundation, 2012T50138, Activation of C-H bond by transition metal doped oxide clusters before and after, 150,000, 2012.04-2013.02, Host, Completed.
13. The 49th batch of Postdoctoral Science Foundation Project (Second class)20110490601, Adsorption and Reaction of water molecules on Vanadium oxygen clusters, 30,000, 2011.03-2012.03, host, completed.
Publication status:
1.Chen, J. J.; Wang, S. D.; Li, Z. Y.; Li, X. N.; * He, S. G. Selective Reduction of NO into N2 Catalyzed by Rh1-Doped Cluster Anions RhCe2O3–5–. J. Am. Chem. Soc. 2023, accept.
2.He, X. Y.; Liu, Y. Z.; Chen, J. J.; Lan, X.; Li, X. N.; * He, S. G. Size-Dependent Reactivity of Con− (n = 5−25) Cluster Anions toward Carbon Dioxide. J. Phys. Chem. Lett. 2023, 14, 6948.
3.Wang, S. D.; Chen, J. J.; Ma, T. M.; Li, X. N.; * He, S. G. Catalytic NO Reduction by Noble-Metal-Free Vanadium−Aluminum Oxide Cluster Anions. J. Phys. Chem. Lett. 2023, 14, 4388.
4.Chen, J. J.; Liu, Y. Z.; Liu, Q. Y.; Li, X. N.; * He, S. G.* Single Ti3+ Ion Catalyzes NO Reduction on Stoichiometric Titanium Oxide Cluster Anions (TiO2)n− (n = 1−11). ACS Catal. 2022, 12, 8768.
5.Chen, J. J.; Li, X. N.; * Mou, L. H.; Liu, Q. Y.; He, S. G.* Catalytic conversion of NO and CO into N2 and CO2 by rhodium–aluminum oxides in the gas phase. J. Mater. Chem. A 2022, 10, 6031.
6.Chen, L. S.; Liu, Y. Z.; Li, X. N.; * Chen, J. J.; Jiang, G. D.; Ma, T. M.; * He, S. G.* An IrVO4+ Cluster Catalytically Oxidizes Four CO Molecules: Importance of Ir−V Multiple Bonding. J. Phys. Chem. Lett. 2021, 12, 6519.
7.Chen, J. J.; Li, X. N.; * Liu, Q. Y.; Wei, G. P.; Yang ,Y.; Li, Z. Y.; He, S. G.* Water Gas Shift Reaction Catalyzed by Rhodium−Manganese Oxide Cluster Anions. J. Phys. Chem. Lett. 2021, 12, 8513.
8.Chen, J.-J.; Li, X.-N.; * Chen, Q.; Jiang, L.-X.; He, S.-G. Neutral Au1Doped Cluster Catalysts AuTi2O3−6 for CO Oxidation by O2. J. Am. Chem. Soc. 2019, 141, 2027.
9.Wang, L. N.; Li, X.-N.; * He, S.-G. Catalytic CO Oxidation by Noble-Metal-Free Ni2VO4,5− Clusters: A CO Self-Promoted Mechanism. J. Phys. Chem. Lett. 2019, 10, 1133.
10.Wang, L.-N.; Li, X.-N.; * Jiang, L.-X.; Yang, B.; Liu, Q.-Y.; Xu, H.-G.; Zheng, W.-J.; * He, S.-G.* Catalytic CO oxidation by O2 Mediated by Noble-Metal-Free Cluster Anions Cu2VO3-5–. Angew. Chem. Int. Ed. 2018, 57, 3349.
11.Zou, X.-P.; # Wang, L.-N.; # Li, X.-N.; * Liu, Q.-Y.; Zhao, Y.-X.; Ma, T.-M.; * He, S.-G.* Noble-Metal-Free Single-Atom Catalysts CuAl4O7-9– for CO Oxidation by O2. Angew. Chem. Int. Ed. 2018, 57, 10989.
12.Jiang, L.-X.; # Zhao, C.; # Li, X.-N.; * Chen, H.; * He, S.-G.* Formation of Gas-Formate in Thermal Reactions of Carbon Dioxide with Diatomic Iron Hydride Anions. Angew. Chem. Int. Ed. 2017, 56, 4187.
13.Li, X.-N.; Yuan, Z.; Zhang, H.-M.; He, S.-G.* A Nine-atom Rhodium-aluminum Oxide Cluster Oxidizes Five Carbon Monoxide Molecules. Nat. Commun. 2016, 7, 11404.
14. Li, X.-N.; Yuan, Z.; He, S.-G.* CO Oxidation Promoted by Gold Atoms Supported on Titanium Oxide Cluster Anions. J. Am. Chem. Soc. 2014, 136, 3617.
15.Li, Z.-Y.; Yuan, Z.; Li, X.-N.; * Zhao, Y.-X.; He, S.-G.* CO Oxidation Catalyzed by Single Gold Atoms Supported on Aluminum Oxide Clusters. J. Am. Chem. Soc. 2014, 136, 14307.