Zirconium Phosphates of Variable Dimension Templated by Ethylene Diamine: Crystal Structures of 1-D [enH2][Zr(HPO4)3] and 2-D [enH2]0.5[Zr(PO4)(HPO4)]

Herman H.Y. Sung; Jihong Yu; Ian D. Williams

doi:10.1006/jssc.1998.7827

Zirconium Phosphates of Variable Dimension Templated by Ethylene Diamine: Crystal Structures of 1-D [enH₂][Zr(HPO₄)₃] and 2-D [enH₂]_0.5[Zr(PO₄)(HPO₄)]

Herman H.Y. Sung^*, Jihong Yu, Ian D. Williams

^*此作品的通讯作者

Hong Kong University of Science and Technology

科研成果: 期刊稿件 › 文章 › 同行评审

38 引用（Scopus）

摘要

Hydrothermal reaction of Zr(OPr)₄with H₃PO₄in the presence of ethylene diamine and HF yields three crystalline phases; the 1-D [enH₂][Zr(HPO₄)₃], 1, which can grow as needles over 1 mm in length, the 2-D [enH₂]_0.5[Zr(PO₄)(HPO₄)], 2, which is found as thin plates, and the previously reported fluorinated 3-D open-framework compound [enH₂]_0.5[Zr₂(PO₄) ₂(HPO₄)F]. H₂O, 3. The 1-D phase is the first of its type, with each Zr linked to neighboring metal atoms in the chain by three bridging phosphate groups via Zr-O-P-O-Zr linkages. Its crystals are monoclinic, space groupC2/c,a=8.996(3),b=15.373(5),c=9.582(4) Å,β=102.97(2)°,V=1287(1) Å³. Compound 2 is orthorhombic, space groupPnnm,a=24.087(4),b=5.381(1),c=6.660(1) Å,V=863.0(4) Å³. It is related to the 'double layer' sheet compoundγ-ZrP and its ion exchanged analogues.

源语言	英语
页（从-至）	46-55
页数	10
期刊	Journal of Solid State Chemistry
卷	140
期	1
DOI	https://doi.org/10.1006/jssc.1998.7827
出版状态	已出版 - 10月 1998
已对外发布	是

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@article{343613162a744f9c8bccaaa4c07be727,

title = "Zirconium Phosphates of Variable Dimension Templated by Ethylene Diamine: Crystal Structures of 1-D [enH2][Zr(HPO4)3] and 2-D [enH2]0.5[Zr(PO4)(HPO4)]",

abstract = "Hydrothermal reaction of Zr(OPr)4with H3PO4in the presence of ethylene diamine and HF yields three crystalline phases; the 1-D [enH2][Zr(HPO4)3], 1, which can grow as needles over 1 mm in length, the 2-D [enH2]0.5[Zr(PO4)(HPO4)], 2, which is found as thin plates, and the previously reported fluorinated 3-D open-framework compound [enH2]0.5[Zr2(PO4) 2(HPO4)F]. H2O, 3. The 1-D phase is the first of its type, with each Zr linked to neighboring metal atoms in the chain by three bridging phosphate groups via Zr-O-P-O-Zr linkages. Its crystals are monoclinic, space groupC2/c,a=8.996(3),b=15.373(5),c=9.582(4) {\AA},β=102.97(2)°,V=1287(1) {\AA}3. Compound 2 is orthorhombic, space groupPnnm,a=24.087(4),b=5.381(1),c=6.660(1) {\AA},V=863.0(4) {\AA}3. It is related to the 'double layer' sheet compoundγ-ZrP and its ion exchanged analogues.",

author = "Sung, {Herman H.Y.} and Jihong Yu and Williams, {Ian D.}",

year = "1998",

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doi = "10.1006/jssc.1998.7827",

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T1 - Zirconium Phosphates of Variable Dimension Templated by Ethylene Diamine

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AU - Sung, Herman H.Y.

AU - Yu, Jihong

AU - Williams, Ian D.

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N2 - Hydrothermal reaction of Zr(OPr)4with H3PO4in the presence of ethylene diamine and HF yields three crystalline phases; the 1-D [enH2][Zr(HPO4)3], 1, which can grow as needles over 1 mm in length, the 2-D [enH2]0.5[Zr(PO4)(HPO4)], 2, which is found as thin plates, and the previously reported fluorinated 3-D open-framework compound [enH2]0.5[Zr2(PO4) 2(HPO4)F]. H2O, 3. The 1-D phase is the first of its type, with each Zr linked to neighboring metal atoms in the chain by three bridging phosphate groups via Zr-O-P-O-Zr linkages. Its crystals are monoclinic, space groupC2/c,a=8.996(3),b=15.373(5),c=9.582(4) Å,β=102.97(2)°,V=1287(1) Å3. Compound 2 is orthorhombic, space groupPnnm,a=24.087(4),b=5.381(1),c=6.660(1) Å,V=863.0(4) Å3. It is related to the 'double layer' sheet compoundγ-ZrP and its ion exchanged analogues.

AB - Hydrothermal reaction of Zr(OPr)4with H3PO4in the presence of ethylene diamine and HF yields three crystalline phases; the 1-D [enH2][Zr(HPO4)3], 1, which can grow as needles over 1 mm in length, the 2-D [enH2]0.5[Zr(PO4)(HPO4)], 2, which is found as thin plates, and the previously reported fluorinated 3-D open-framework compound [enH2]0.5[Zr2(PO4) 2(HPO4)F]. H2O, 3. The 1-D phase is the first of its type, with each Zr linked to neighboring metal atoms in the chain by three bridging phosphate groups via Zr-O-P-O-Zr linkages. Its crystals are monoclinic, space groupC2/c,a=8.996(3),b=15.373(5),c=9.582(4) Å,β=102.97(2)°,V=1287(1) Å3. Compound 2 is orthorhombic, space groupPnnm,a=24.087(4),b=5.381(1),c=6.660(1) Å,V=863.0(4) Å3. It is related to the 'double layer' sheet compoundγ-ZrP and its ion exchanged analogues.

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Zirconium Phosphates of Variable Dimension Templated by Ethylene Diamine: Crystal Structures of 1-D [enH2][Zr(HPO4)3] and 2-D [enH2]0.5[Zr(PO4)(HPO4)]

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Zirconium Phosphates of Variable Dimension Templated by Ethylene Diamine: Crystal Structures of 1-D [enH₂][Zr(HPO₄)₃] and 2-D [enH₂]_0.5[Zr(PO₄)(HPO₄)]