Zigzag on a zigzag: Trap of hydrogen-bonded water molecules in a luminescent metal-organic network

Kunlin Huang; Yanting He; Xueli Niu; Xiangyu Chen; Yingnan Chi; Yun Gong; Changwen Hu

doi:10.1016/j.inoche.2006.07.042

Zigzag on a zigzag: Trap of hydrogen-bonded water molecules in a luminescent metal-organic network

Kunlin Huang
, Yanting He
, Xueli Niu
, Xiangyu Chen
, Yingnan Chi
, Yun Gong
, Changwen Hu^*

^*此作品的通讯作者

化学与化工学院

Beijing Institute of Technology
Chongqing Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

24 引用（Scopus）

摘要

A four-connected 2-D metal-organic coordination polymer {[Cd(mpdc)(phen)] · H₂O}(mpdc = 2,6-dimethylpyridine-3,5-dicarboxylate, phen = 1,10-phenanthroline) has been assemblied from cadmium ions and two kinds of organic ligands under hydrothermal conditions, characterized by single-crystal X-ray diffraction analysis. The 2-D metal-organic network was constructed from binuclear [Cd(O₅N₂)]₂ clusters bridged by mpdc^2- ligands. The most interesting is that water molecules trapped by the 2-D network look as if its motif is projected from the zigzag arrangement of cadmium atoms in the 2-D network via hydrogen bonding interactions. In addition, new compound exhibits strong luminescence at λ_max = 525 nm upon excitation at 367 nm.

源语言	英语
页（从-至）	1243-1246
页数	4
期刊	Inorganic Chemistry Communications
卷	9
期	12
DOI	https://doi.org/10.1016/j.inoche.2006.07.042
出版状态	已出版 - 12月 2006

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@article{f1b0b8e28b454df18ce744500c6291a4,

title = "Zigzag on a zigzag: Trap of hydrogen-bonded water molecules in a luminescent metal-organic network",

abstract = "A four-connected 2-D metal-organic coordination polymer \{[Cd(mpdc)(phen)] · H2O\}(mpdc = 2,6-dimethylpyridine-3,5-dicarboxylate, phen = 1,10-phenanthroline) has been assemblied from cadmium ions and two kinds of organic ligands under hydrothermal conditions, characterized by single-crystal X-ray diffraction analysis. The 2-D metal-organic network was constructed from binuclear [Cd(O5N2)]2 clusters bridged by mpdc2- ligands. The most interesting is that water molecules trapped by the 2-D network look as if its motif is projected from the zigzag arrangement of cadmium atoms in the 2-D network via hydrogen bonding interactions. In addition, new compound exhibits strong luminescence at λmax = 525 nm upon excitation at 367 nm.",

keywords = "Cadmium, Carboxylate, Coordination polymer, Hydrothermal reaction, Luminescence",

author = "Kunlin Huang and Yanting He and Xueli Niu and Xiangyu Chen and Yingnan Chi and Yun Gong and Changwen Hu",

year = "2006",

month = dec,

doi = "10.1016/j.inoche.2006.07.042",

language = "English",

volume = "9",

pages = "1243--1246",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "12",

}

TY - JOUR

T1 - Zigzag on a zigzag

T2 - Trap of hydrogen-bonded water molecules in a luminescent metal-organic network

AU - Huang, Kunlin

AU - He, Yanting

AU - Niu, Xueli

AU - Chen, Xiangyu

AU - Chi, Yingnan

AU - Gong, Yun

AU - Hu, Changwen

PY - 2006/12

Y1 - 2006/12

N2 - A four-connected 2-D metal-organic coordination polymer {[Cd(mpdc)(phen)] · H2O}(mpdc = 2,6-dimethylpyridine-3,5-dicarboxylate, phen = 1,10-phenanthroline) has been assemblied from cadmium ions and two kinds of organic ligands under hydrothermal conditions, characterized by single-crystal X-ray diffraction analysis. The 2-D metal-organic network was constructed from binuclear [Cd(O5N2)]2 clusters bridged by mpdc2- ligands. The most interesting is that water molecules trapped by the 2-D network look as if its motif is projected from the zigzag arrangement of cadmium atoms in the 2-D network via hydrogen bonding interactions. In addition, new compound exhibits strong luminescence at λmax = 525 nm upon excitation at 367 nm.

AB - A four-connected 2-D metal-organic coordination polymer {[Cd(mpdc)(phen)] · H2O}(mpdc = 2,6-dimethylpyridine-3,5-dicarboxylate, phen = 1,10-phenanthroline) has been assemblied from cadmium ions and two kinds of organic ligands under hydrothermal conditions, characterized by single-crystal X-ray diffraction analysis. The 2-D metal-organic network was constructed from binuclear [Cd(O5N2)]2 clusters bridged by mpdc2- ligands. The most interesting is that water molecules trapped by the 2-D network look as if its motif is projected from the zigzag arrangement of cadmium atoms in the 2-D network via hydrogen bonding interactions. In addition, new compound exhibits strong luminescence at λmax = 525 nm upon excitation at 367 nm.

KW - Cadmium

KW - Carboxylate

KW - Coordination polymer

KW - Hydrothermal reaction

KW - Luminescence

UR - https://www.scopus.com/pages/publications/33750956564

U2 - 10.1016/j.inoche.2006.07.042

DO - 10.1016/j.inoche.2006.07.042

M3 - Article

AN - SCOPUS:33750956564

SN - 1387-7003

VL - 9

SP - 1243

EP - 1246

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 12

ER -

Zigzag on a zigzag: Trap of hydrogen-bonded water molecules in a luminescent metal-organic network

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