TY - JOUR
T1 - Unusual T4(1) water chain stabilized in the one-dimensional chains of a copper(II) coordination polymer
AU - Jin, Yi
AU - Che, Yunxia
AU - Batten, Stuart R.
AU - Chen, Pangkuan
AU - Zheng, Jimin
PY - 2007
Y1 - 2007
N2 - A novel T4(1) water chain in a new CuII coordination polymer, {[Cu(C4H6N2)2(C4H 2O4)] (H2O)3}n (1, where C4H6N2 = 2-methylimidazole, C4H 2O4 = maleate), has been synthesized and structurally characterized by single-crystal X-ray diffraction. Thermogravimetry, infrared spectroscopy, elemental analysis, and magnetic analysis have also been used to characterize 1. Complex 1 crystallizes in the trigonal space group P3 221, and the 1-D chains composed of cyclic water tetramers play an important role in stabilizing the overall polymeric structure. Furthermore, this 1-D water chain presents an unusual association mode of water molecules.
AB - A novel T4(1) water chain in a new CuII coordination polymer, {[Cu(C4H6N2)2(C4H 2O4)] (H2O)3}n (1, where C4H6N2 = 2-methylimidazole, C4H 2O4 = maleate), has been synthesized and structurally characterized by single-crystal X-ray diffraction. Thermogravimetry, infrared spectroscopy, elemental analysis, and magnetic analysis have also been used to characterize 1. Complex 1 crystallizes in the trigonal space group P3 221, and the 1-D chains composed of cyclic water tetramers play an important role in stabilizing the overall polymeric structure. Furthermore, this 1-D water chain presents an unusual association mode of water molecules.
KW - Coordination polymers
KW - One dimensional
KW - Self assembly
KW - Water chain
UR - https://www.scopus.com/pages/publications/34250843211
U2 - 10.1002/ejic.200601108
DO - 10.1002/ejic.200601108
M3 - Article
AN - SCOPUS:34250843211
SN - 1434-1948
SP - 1925
EP - 1929
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
IS - 13
ER -