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Two photoluminescent coordination polymers based on naphthalene-1,4,5,8- tetracarboxylic acid 4,5-anhydride

  • Yanqing Xu
  • , Daqiang Yuan
  • , Benlai Wu
  • , Feilong Jiang
  • , Youfu Zhou
  • , Maochun Hong*
  • *此作品的通讯作者
  • CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件文章同行评审

摘要

Two cadmium(II)-ntcaa coordination polymers, [Cd(phen)(ntcaa)(H 2O)2]n (1) and [Cd2(4,4′-bpy) (ntcaa)2]n (2) (ntcaa = naphthalene-1,4,5,8- tetracarboxylic acid 4,5-anhydride, phen = 1,10-phenanthroline, 4,4′-bpy = 4,4′-bipyridine), were synthesized via hydrothermal method. The structure of compound 1 is a neutral comb-like chain with π-π interactions between the phen and naphthalene aromatic rings, while that of 2 possesses an interesting baluster structure composed of helix chain as post and 4,4′-bpy as connector. Photoluminescent investigations reveal that both compounds exhibit strong emissions in the solid state.

源语言英语
页(从-至)651-655
页数5
期刊Inorganic Chemistry Communications
8
7
DOI
出版状态已出版 - 7月 2005
已对外发布

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