Two novel pillared-layer lanthanide borates built by Ln@B12O28/29 ring clusters and dicarboxylate linkers (Ln = Pr, Nd)

Lei Lei Li; Rui Pan; Jun Wei Zhao; Bai Feng Yang; Guo Yu Yang

doi:10.1039/c6dt01909a

Two novel pillared-layer lanthanide borates built by Ln@B₁₂O_28/29 ring clusters and dicarboxylate linkers (Ln = Pr, Nd)

Lei Lei Li
, Rui Pan
, Jun Wei Zhao
, Bai Feng Yang
, Guo Yu Yang^*

^*此作品的通讯作者

化学与化工学院

Beijing Institute of Technology
Henan University
Shantou University

科研成果: 期刊稿件 › 文章 › 同行评审

26 引用（Scopus）

摘要

Two organic-inorganic hybrid pillared-layer lanthanide borates, [Ln₂B₈O₁₂(bdc)₃(H₂O)]·H₂O (Ln = Pr, 1; Nd, 2; H₂bdc = 1,4-benzene dicarboxylic acid), have been made, in which inorganic layers are built by Ln-centred oxoboron ring clusters, Ln@B₁₂O₂₈/Ln@B₁₂O₂₉, while the pillars are organic bdc linkers. Interestingly, two types of linkages, Ln-O-C and B-O-C bonds, exist in the structures, showing firstly novel linking modes between inorganic polyborate and organic dicarboxylate.

源语言	英语
页（从-至）	11628-11632
页数	5
期刊	Dalton Transactions
卷	45
期	29
DOI	https://doi.org/10.1039/c6dt01909a
出版状态	已出版 - 2016

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10.1039/c6dt01909a

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引用此

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title = "Two novel pillared-layer lanthanide borates built by Ln@B12O28/29 ring clusters and dicarboxylate linkers (Ln = Pr, Nd)",

abstract = "Two organic-inorganic hybrid pillared-layer lanthanide borates, [Ln2B8O12(bdc)3(H2O)]·H2O (Ln = Pr, 1; Nd, 2; H2bdc = 1,4-benzene dicarboxylic acid), have been made, in which inorganic layers are built by Ln-centred oxoboron ring clusters, Ln@B12O28/Ln@B12O29, while the pillars are organic bdc linkers. Interestingly, two types of linkages, Ln-O-C and B-O-C bonds, exist in the structures, showing firstly novel linking modes between inorganic polyborate and organic dicarboxylate.",

author = "Li, \{Lei Lei\} and Rui Pan and Zhao, \{Jun Wei\} and Yang, \{Bai Feng\} and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright}2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6dt01909a",

language = "English",

volume = "45",

pages = "11628--11632",

journal = "Dalton Transactions",

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AU - Li, Lei Lei

AU - Pan, Rui

AU - Zhao, Jun Wei

AU - Yang, Bai Feng

AU - Yang, Guo Yu

PY - 2016

Y1 - 2016

N2 - Two organic-inorganic hybrid pillared-layer lanthanide borates, [Ln2B8O12(bdc)3(H2O)]·H2O (Ln = Pr, 1; Nd, 2; H2bdc = 1,4-benzene dicarboxylic acid), have been made, in which inorganic layers are built by Ln-centred oxoboron ring clusters, Ln@B12O28/Ln@B12O29, while the pillars are organic bdc linkers. Interestingly, two types of linkages, Ln-O-C and B-O-C bonds, exist in the structures, showing firstly novel linking modes between inorganic polyborate and organic dicarboxylate.

AB - Two organic-inorganic hybrid pillared-layer lanthanide borates, [Ln2B8O12(bdc)3(H2O)]·H2O (Ln = Pr, 1; Nd, 2; H2bdc = 1,4-benzene dicarboxylic acid), have been made, in which inorganic layers are built by Ln-centred oxoboron ring clusters, Ln@B12O28/Ln@B12O29, while the pillars are organic bdc linkers. Interestingly, two types of linkages, Ln-O-C and B-O-C bonds, exist in the structures, showing firstly novel linking modes between inorganic polyborate and organic dicarboxylate.

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DO - 10.1039/c6dt01909a

M3 - Article

AN - SCOPUS:84979285133

SN - 1477-9226

VL - 45

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EP - 11632

JO - Dalton Transactions

JF - Dalton Transactions

IS - 29

ER -

Two novel pillared-layer lanthanide borates built by Ln@B12O28/29 ring clusters and dicarboxylate linkers (Ln = Pr, Nd)

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Two novel pillared-layer lanthanide borates built by Ln@B₁₂O_28/29 ring clusters and dicarboxylate linkers (Ln = Pr, Nd)