Two novel 1-D organic-inorganic composite phosphotungstates constructed from [Ln(α-PW11O39)2]11- units and [Cu(en)2]2+ Bridges (Ln = CeIII/ErIII)

Bing Li; Jun Wei Zhao; Shou Tian Zheng; Guo Yu Yang

doi:10.1007/s10876-009-0235-8

Two novel 1-D organic-inorganic composite phosphotungstates constructed from [Ln(α-PW₁₁O₃₉)₂]^11- units and [Cu(en)₂]²⁺ Bridges (Ln = Ce^III/Er^III)

Bing Li
, Jun Wei Zhao
, Shou Tian Zheng
, Guo Yu Yang^*

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter
Zhejiang Agriculture and Forestry University

科研成果: 期刊稿件 › 文章 › 同行评审

24 引用（Scopus）

摘要

Two novel organic-inorganic composite phosphotungstates, [H₉{Ce(α-PW₁₁O₃₉)₂}Cu(en)₂] · 6H₂O (1) and H₇[Cu(en)₂{Er(α-PW₁₁O₃₉)₂}Cu(en)₂] · 12H₂O (2) (en = ethylenediamine) have been synthesized by the hydrothermal reaction of the trivacant Keggin polyoxoanion [α-A-PW₉O₃₄]^9- with Ce^III or Er^III ions in the presence of Cu²⁺ ions and en, and structurally characterized by IR spectra, elemental analysis and thermogravimetric analysis. X-ray crystallographic analyses indicate that they are all built by sandwich-type [Ln(α-PW₁₁O₃₉)₂]^11- (Ln = Ce^III, Er^III) polyoxoanions and [Cu(en)₂]²⁺ cations generating infinite one-dimensional arrangements. To our knowledge, this 1-D chain structures constituted by mono-Ln sandwiched POM units and transition-metal complex cations are very rare.

源语言	英语
页（从-至）	503-513
页数	11
期刊	Journal of Cluster Science
卷	20
期	3
DOI	https://doi.org/10.1007/s10876-009-0235-8
出版状态	已出版 - 2009
已对外发布	是

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@article{1f4dfaabf97348f79a012c73978c7b50,

title = "Two novel 1-D organic-inorganic composite phosphotungstates constructed from [Ln(α-PW11O39)2]11- units and [Cu(en)2]2+ Bridges (Ln = CeIII/ErIII)",

abstract = "Two novel organic-inorganic composite phosphotungstates, [H9\{Ce(α-PW11O39)2\}Cu(en)2] · 6H2O (1) and H7[Cu(en)2\{Er(α-PW11O39)2\}Cu(en)2] · 12H2O (2) (en = ethylenediamine) have been synthesized by the hydrothermal reaction of the trivacant Keggin polyoxoanion [α-A-PW9O34]9- with CeIII or ErIII ions in the presence of Cu2+ ions and en, and structurally characterized by IR spectra, elemental analysis and thermogravimetric analysis. X-ray crystallographic analyses indicate that they are all built by sandwich-type [Ln(α-PW11O39)2]11- (Ln = CeIII, ErIII) polyoxoanions and [Cu(en)2]2+ cations generating infinite one-dimensional arrangements. To our knowledge, this 1-D chain structures constituted by mono-Ln sandwiched POM units and transition-metal complex cations are very rare.",

keywords = "Hydrothermal reaction, Organic-inorganic hybrid, Polyoxometalates, Trivacant Keggin derivatives",

author = "Bing Li and Zhao, \{Jun Wei\} and Zheng, \{Shou Tian\} and Yang, \{Guo Yu\}",

year = "2009",

doi = "10.1007/s10876-009-0235-8",

language = "English",

volume = "20",

pages = "503--513",

journal = "Journal of Cluster Science",

issn = "1040-7278",

publisher = "Springer New York",

number = "3",

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T1 - Two novel 1-D organic-inorganic composite phosphotungstates constructed from [Ln(α-PW11O39)2]11- units and [Cu(en)2]2+ Bridges (Ln = CeIII/ErIII)

AU - Li, Bing

AU - Zhao, Jun Wei

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2009

Y1 - 2009

N2 - Two novel organic-inorganic composite phosphotungstates, [H9{Ce(α-PW11O39)2}Cu(en)2] · 6H2O (1) and H7[Cu(en)2{Er(α-PW11O39)2}Cu(en)2] · 12H2O (2) (en = ethylenediamine) have been synthesized by the hydrothermal reaction of the trivacant Keggin polyoxoanion [α-A-PW9O34]9- with CeIII or ErIII ions in the presence of Cu2+ ions and en, and structurally characterized by IR spectra, elemental analysis and thermogravimetric analysis. X-ray crystallographic analyses indicate that they are all built by sandwich-type [Ln(α-PW11O39)2]11- (Ln = CeIII, ErIII) polyoxoanions and [Cu(en)2]2+ cations generating infinite one-dimensional arrangements. To our knowledge, this 1-D chain structures constituted by mono-Ln sandwiched POM units and transition-metal complex cations are very rare.

AB - Two novel organic-inorganic composite phosphotungstates, [H9{Ce(α-PW11O39)2}Cu(en)2] · 6H2O (1) and H7[Cu(en)2{Er(α-PW11O39)2}Cu(en)2] · 12H2O (2) (en = ethylenediamine) have been synthesized by the hydrothermal reaction of the trivacant Keggin polyoxoanion [α-A-PW9O34]9- with CeIII or ErIII ions in the presence of Cu2+ ions and en, and structurally characterized by IR spectra, elemental analysis and thermogravimetric analysis. X-ray crystallographic analyses indicate that they are all built by sandwich-type [Ln(α-PW11O39)2]11- (Ln = CeIII, ErIII) polyoxoanions and [Cu(en)2]2+ cations generating infinite one-dimensional arrangements. To our knowledge, this 1-D chain structures constituted by mono-Ln sandwiched POM units and transition-metal complex cations are very rare.

KW - Hydrothermal reaction

KW - Organic-inorganic hybrid

KW - Polyoxometalates

KW - Trivacant Keggin derivatives

UR - https://www.scopus.com/pages/publications/70350028553

U2 - 10.1007/s10876-009-0235-8

DO - 10.1007/s10876-009-0235-8

M3 - Article

AN - SCOPUS:70350028553

SN - 1040-7278

VL - 20

SP - 503

EP - 513

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 3

ER -

Two novel 1-D organic-inorganic composite phosphotungstates constructed from [Ln(α-PW11O39)2]11- units and [Cu(en)2]2+ Bridges (Ln = CeIII/ErIII)

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Two novel 1-D organic-inorganic composite phosphotungstates constructed from [Ln(α-PW₁₁O₃₉)₂]^11- units and [Cu(en)₂]²⁺ Bridges (Ln = Ce^III/Er^III)