Tris(2,2'-bipyridine)nickel(II) diperchlorate

Youfu Zhou; Xing Li; Yanqing Xu; Rong Cao; Maochun Hong

doi:10.1107/S1600536803008778

Tris(2,2'-bipyridine)nickel(II) diperchlorate

Youfu Zhou
, Xing Li
, Yanqing Xu
, Rong Cao
, Maochun Hong^*

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

11 引用（Scopus）

摘要

The title compound, [Ni(C₁₀H₈N₂) ₃](ClO₄)₂, is built up of monomeric [Ni(bpy)₃]²⁺ cations (bpy = 2,2'-bipyridine) and two perchlorate anions. The asymmetric unit is one half cation and one anion, a twofold rotation axis passing through the Ni atom and bisecting one bpy ligand. The Ni^II ion is coordinated by six N atoms from three chelating bpy ligands in a highly distorted octahedral geometry, with Ni-N bond lengths ranging from 2.071 (4) to 2.091 (4) Å.

源语言	英语
页（从-至）	m300-m302
期刊	Acta Crystallographica Section E: Structure Reports Online
卷	59
期	5
DOI	https://doi.org/10.1107/S1600536803008778
出版状态	已出版 - 5月 2003
已对外发布	是

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@article{6f15a8c785214137b9e6bf33f718b808,

title = "Tris(2,2'-bipyridine)nickel(II) diperchlorate",

abstract = "The title compound, [Ni(C10H8N2) 3](ClO4)2, is built up of monomeric [Ni(bpy)3]2+ cations (bpy = 2,2'-bipyridine) and two perchlorate anions. The asymmetric unit is one half cation and one anion, a twofold rotation axis passing through the Ni atom and bisecting one bpy ligand. The NiII ion is coordinated by six N atoms from three chelating bpy ligands in a highly distorted octahedral geometry, with Ni-N bond lengths ranging from 2.071 (4) to 2.091 (4) {\AA}.",

author = "Youfu Zhou and Xing Li and Yanqing Xu and Rong Cao and Maochun Hong",

year = "2003",

month = may,

doi = "10.1107/S1600536803008778",

language = "English",

volume = "59",

pages = "m300--m302",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "5",

}

TY - JOUR

T1 - Tris(2,2'-bipyridine)nickel(II) diperchlorate

AU - Zhou, Youfu

AU - Li, Xing

AU - Xu, Yanqing

AU - Cao, Rong

AU - Hong, Maochun

PY - 2003/5

Y1 - 2003/5

N2 - The title compound, [Ni(C10H8N2) 3](ClO4)2, is built up of monomeric [Ni(bpy)3]2+ cations (bpy = 2,2'-bipyridine) and two perchlorate anions. The asymmetric unit is one half cation and one anion, a twofold rotation axis passing through the Ni atom and bisecting one bpy ligand. The NiII ion is coordinated by six N atoms from three chelating bpy ligands in a highly distorted octahedral geometry, with Ni-N bond lengths ranging from 2.071 (4) to 2.091 (4) Å.

AB - The title compound, [Ni(C10H8N2) 3](ClO4)2, is built up of monomeric [Ni(bpy)3]2+ cations (bpy = 2,2'-bipyridine) and two perchlorate anions. The asymmetric unit is one half cation and one anion, a twofold rotation axis passing through the Ni atom and bisecting one bpy ligand. The NiII ion is coordinated by six N atoms from three chelating bpy ligands in a highly distorted octahedral geometry, with Ni-N bond lengths ranging from 2.071 (4) to 2.091 (4) Å.

UR - https://www.scopus.com/pages/publications/18444379957

U2 - 10.1107/S1600536803008778

DO - 10.1107/S1600536803008778

M3 - Article

AN - SCOPUS:18444379957

SN - 1600-5368

VL - 59

SP - m300-m302

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 5

ER -

Tris(2,2'-bipyridine)nickel(II) diperchlorate

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