Ti7-containing, tetrahedral 36-tungsto-4-arsenate(iii) [Ti6(TiO6)(AsW9O33)4]20-

Kai Yao Wang; Bassem S. Bassil; Zheng Guo Lin; Ali Haider; Jie Cao; Holger Stephan; Katrin Viehweger; Ulrich Kortz

doi:10.1039/c4dt02494j

Ti₇-containing, tetrahedral 36-tungsto-4-arsenate(iii) [Ti₆(TiO₆)(AsW₉O₃₃)₄]^20-

Kai Yao Wang
, Bassem S. Bassil
, Zheng Guo Lin
, Ali Haider
, Jie Cao
, Holger Stephan
, Katrin Viehweger
, Ulrich Kortz^*

^*此作品的通讯作者

科研成果: 期刊稿件 › 文章 › 同行评审

24 引用（Scopus）

摘要

We have prepared the Ti₇-containing, tetrahedral 36-tungsto-4-arsenate(iii) [Ti₆(TiO₆)(AsW₉O₃₃)₄]^20- (1) by a simple, one pot procedure. Polyanion 1 contains a novel Ti₇-core, comprising a central TiO₆ octahedron surrounded by six TiO₅ square-pyramids, and capped by four {As^IIIW₉} trilacunary fragments. The title polyanion is solution-stable, as shown by ¹⁸³W NMR and mass spectrometry, and exhibits interesting biological properties.

源语言	英语
页（从-至）	16143-16146
页数	4
期刊	Dalton Transactions
卷	43
期	43
DOI	https://doi.org/10.1039/c4dt02494j
出版状态	已出版 - 21 11月 2014
已对外发布	是

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10.1039/c4dt02494j

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@article{8901450a7022425b936ce257b884a11d,

title = "Ti7-containing, tetrahedral 36-tungsto-4-arsenate(iii) [Ti6(TiO6)(AsW9O33)4]20-",

abstract = "We have prepared the Ti7-containing, tetrahedral 36-tungsto-4-arsenate(iii) [Ti6(TiO6)(AsW9O33)4]20- (1) by a simple, one pot procedure. Polyanion 1 contains a novel Ti7-core, comprising a central TiO6 octahedron surrounded by six TiO5 square-pyramids, and capped by four \{AsIIIW9\} trilacunary fragments. The title polyanion is solution-stable, as shown by 183W NMR and mass spectrometry, and exhibits interesting biological properties.",

author = "Wang, \{Kai Yao\} and Bassil, \{Bassem S.\} and Lin, \{Zheng Guo\} and Ali Haider and Jie Cao and Holger Stephan and Katrin Viehweger and Ulrich Kortz",

note = "Publisher Copyright: {\textcopyright} 2014 the Partner Organisations.",

year = "2014",

month = nov,

day = "21",

doi = "10.1039/c4dt02494j",

language = "English",

volume = "43",

pages = "16143--16146",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "43",

}

TY - JOUR

T1 - Ti7-containing, tetrahedral 36-tungsto-4-arsenate(iii) [Ti6(TiO6)(AsW9O33)4]20-

AU - Wang, Kai Yao

AU - Bassil, Bassem S.

AU - Lin, Zheng Guo

AU - Haider, Ali

AU - Cao, Jie

AU - Stephan, Holger

AU - Viehweger, Katrin

AU - Kortz, Ulrich

PY - 2014/11/21

Y1 - 2014/11/21

N2 - We have prepared the Ti7-containing, tetrahedral 36-tungsto-4-arsenate(iii) [Ti6(TiO6)(AsW9O33)4]20- (1) by a simple, one pot procedure. Polyanion 1 contains a novel Ti7-core, comprising a central TiO6 octahedron surrounded by six TiO5 square-pyramids, and capped by four {AsIIIW9} trilacunary fragments. The title polyanion is solution-stable, as shown by 183W NMR and mass spectrometry, and exhibits interesting biological properties.

AB - We have prepared the Ti7-containing, tetrahedral 36-tungsto-4-arsenate(iii) [Ti6(TiO6)(AsW9O33)4]20- (1) by a simple, one pot procedure. Polyanion 1 contains a novel Ti7-core, comprising a central TiO6 octahedron surrounded by six TiO5 square-pyramids, and capped by four {AsIIIW9} trilacunary fragments. The title polyanion is solution-stable, as shown by 183W NMR and mass spectrometry, and exhibits interesting biological properties.

UR - https://www.scopus.com/pages/publications/84908043052

U2 - 10.1039/c4dt02494j

DO - 10.1039/c4dt02494j

M3 - Article

AN - SCOPUS:84908043052

SN - 1477-9226

VL - 43

SP - 16143

EP - 16146

JO - Dalton Transactions

JF - Dalton Transactions

IS - 43

ER -

Ti7-containing, tetrahedral 36-tungsto-4-arsenate(iii) [Ti6(TiO6)(AsW9O33)4]20-

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Ti₇-containing, tetrahedral 36-tungsto-4-arsenate(iii) [Ti₆(TiO₆)(AsW₉O₃₃)₄]^20-