The synthesis, structure and characterization of V2O6 · H3NCH2CH2NH3

Jia Ning Xu; Guo Yu Yang; De Jun Wang; Wen Ying Ma; Hao Ran Sun; Ji Qing Xu; Xiao Ying Huang

The synthesis, structure and characterization of V₂O₆ · H₃NCH₂CH₂NH₃

Jia Ning Xu
, Guo Yu Yang
, De Jun Wang
, Wen Ying Ma
, Hao Ran Sun
, Ji Qing Xu
, Xiao Ying Huang

Jilin University
CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

A metavanadate in coffee colour, V₂O₆ · H₃NCH₂CH₂NH₃, was synthesized by hydrothermal method and its crystal structure was determined by single crystal X-ray diffraction. Crystal data: monoclinic, space group P2₁/c, a = 0.552 9(2) nm, b=1.290 0(7) nm, c=0. 568 3(2) nm, β=97. 57(3)°, V=0.401 8(3) nm³, F(000)=260, D_c=2.15 g · cm^-3, Z=2, R=0.041, R_w= 0.052. The structure is based on VO₄ tetrahedra sharing two vertex to form a single type of chain running along the c axis. The hydrogen bond (O⋯ H - N) between (VO₃^-)_∞ chains and H₃NCH₂CH₂NH₃²⁺ was formed. IR spectrum confirmed that the ethylenediamine is protonated. The analysis of DRS and SPS are given.

源语言	英语
页（从-至）	x5-1021
期刊	Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
卷	17
期	7
出版状态	已出版 - 1996
已对外发布	是

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@article{ba9347559e5d4ec0aef828e83b33755d,

title = "The synthesis, structure and characterization of V2O6 · H3NCH2CH2NH3",

abstract = "A metavanadate in coffee colour, V2O6 · H3NCH2CH2NH3, was synthesized by hydrothermal method and its crystal structure was determined by single crystal X-ray diffraction. Crystal data: monoclinic, space group P21/c, a = 0.552 9(2) nm, b=1.290 0(7) nm, c=0. 568 3(2) nm, β=97. 57(3)°, V=0.401 8(3) nm3, F(000)=260, Dc=2.15 g · cm-3, Z=2, R=0.041, Rw= 0.052. The structure is based on VO4 tetrahedra sharing two vertex to form a single type of chain running along the c axis. The hydrogen bond (O⋯ H - N) between (VO3-)∞ chains and H3NCH2CH2NH32+ was formed. IR spectrum confirmed that the ethylenediamine is protonated. The analysis of DRS and SPS are given.",

keywords = "Metavanadate, Structure, VO tetrahedra",

author = "Xu, \{Jia Ning\} and Yang, \{Guo Yu\} and Wang, \{De Jun\} and Ma, \{Wen Ying\} and Sun, \{Hao Ran\} and Xu, \{Ji Qing\} and Huang, \{Xiao Ying\}",

year = "1996",

language = "English",

volume = "17",

pages = "x5--1021",

journal = "Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities",

issn = "0251-0790",

publisher = "Higher Education Press Limited Company",

number = "7",

}

TY - JOUR

T1 - The synthesis, structure and characterization of V2O6 · H3NCH2CH2NH3

AU - Xu, Jia Ning

AU - Yang, Guo Yu

AU - Wang, De Jun

AU - Ma, Wen Ying

AU - Sun, Hao Ran

AU - Xu, Ji Qing

AU - Huang, Xiao Ying

PY - 1996

Y1 - 1996

N2 - A metavanadate in coffee colour, V2O6 · H3NCH2CH2NH3, was synthesized by hydrothermal method and its crystal structure was determined by single crystal X-ray diffraction. Crystal data: monoclinic, space group P21/c, a = 0.552 9(2) nm, b=1.290 0(7) nm, c=0. 568 3(2) nm, β=97. 57(3)°, V=0.401 8(3) nm3, F(000)=260, Dc=2.15 g · cm-3, Z=2, R=0.041, Rw= 0.052. The structure is based on VO4 tetrahedra sharing two vertex to form a single type of chain running along the c axis. The hydrogen bond (O⋯ H - N) between (VO3-)∞ chains and H3NCH2CH2NH32+ was formed. IR spectrum confirmed that the ethylenediamine is protonated. The analysis of DRS and SPS are given.

AB - A metavanadate in coffee colour, V2O6 · H3NCH2CH2NH3, was synthesized by hydrothermal method and its crystal structure was determined by single crystal X-ray diffraction. Crystal data: monoclinic, space group P21/c, a = 0.552 9(2) nm, b=1.290 0(7) nm, c=0. 568 3(2) nm, β=97. 57(3)°, V=0.401 8(3) nm3, F(000)=260, Dc=2.15 g · cm-3, Z=2, R=0.041, Rw= 0.052. The structure is based on VO4 tetrahedra sharing two vertex to form a single type of chain running along the c axis. The hydrogen bond (O⋯ H - N) between (VO3-)∞ chains and H3NCH2CH2NH32+ was formed. IR spectrum confirmed that the ethylenediamine is protonated. The analysis of DRS and SPS are given.

KW - Metavanadate

KW - Structure

KW - VO tetrahedra

UR - https://www.scopus.com/pages/publications/2842584624

M3 - Article

AN - SCOPUS:2842584624

SN - 0251-0790

VL - 17

SP - x5-1021

JO - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

JF - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

IS - 7

ER -

The synthesis, structure and characterization of V2O6 · H3NCH2CH2NH3

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The synthesis, structure and characterization of V₂O₆ · H₃NCH₂CH₂NH₃