Synthesis, structure and magnetic property of a two-dimensional stair-like framework: [Ni(μ1,5-dca)2(en)]n

Yan Qing Xu; Da Qiang Yuan; Fei Long Jiang; Ying Xu; You Fu Zhou; Mao Chun Hong

Synthesis, structure and magnetic property of a two-dimensional stair-like framework: [Ni(μ_1,5-dca)₂(en)]_n

Yan Qing Xu^*
, Da Qiang Yuan
, Fei Long Jiang
, Ying Xu
, You Fu Zhou
, Mao Chun Hong

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

1 引用（Scopus）

摘要

A new nickel(II)-dicyanamide compound, [Ni(dca)₂(en)] _n (1) (dca=dicyanamide anion, [N(CN)₂]^-); en=ethylene diamine), has been synthesized and its structure has been determined by single crystal X-ray diffraction analysis. The crystal is monoclinic, space group P2₁/n with unit cell dimensions: a=0.6943(1) nm, b=1.041 5(2) nm, c= 1.4132(2) nm, and β=90.381°, Z=4, V=1.011 10(3) nm³. In this compound, the adjacent nickel atoms are connected by dca all in μ_1,5-bridging mode to form ladder-like units, which are linked with double dca bridges to generate a regular infinite stair-like structure. Temperature-dependent magnetic susceptibility was also characterized for this compound.

源语言	英语
页（从-至）	1245-1248
页数	4
期刊	Chinese Journal of Inorganic Chemistry
卷	20
期	10
出版状态	已出版 - 2004
已对外发布	是

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引用此

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title = "Synthesis, structure and magnetic property of a two-dimensional stair-like framework: [Ni(μ1,5-dca)2(en)]n",

abstract = "A new nickel(II)-dicyanamide compound, [Ni(dca)2(en)] n (1) (dca=dicyanamide anion, [N(CN)2]-); en=ethylene diamine), has been synthesized and its structure has been determined by single crystal X-ray diffraction analysis. The crystal is monoclinic, space group P21/n with unit cell dimensions: a=0.6943(1) nm, b=1.041 5(2) nm, c= 1.4132(2) nm, and β=90.381°, Z=4, V=1.011 10(3) nm3. In this compound, the adjacent nickel atoms are connected by dca all in μ1,5-bridging mode to form ladder-like units, which are linked with double dca bridges to generate a regular infinite stair-like structure. Temperature-dependent magnetic susceptibility was also characterized for this compound.",

keywords = "Coordination polymer, Magnetism, Nickel compound, Stair-like structure",

author = "Xu, \{Yan Qing\} and Yuan, \{Da Qiang\} and Jiang, \{Fei Long\} and Ying Xu and Zhou, \{You Fu\} and Hong, \{Mao Chun\}",

year = "2004",

language = "English",

volume = "20",

pages = "1245--1248",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "10",

}

TY - JOUR

T1 - Synthesis, structure and magnetic property of a two-dimensional stair-like framework

T2 - [Ni(μ1,5-dca)2(en)]n

AU - Xu, Yan Qing

AU - Yuan, Da Qiang

AU - Jiang, Fei Long

AU - Xu, Ying

AU - Zhou, You Fu

AU - Hong, Mao Chun

PY - 2004

Y1 - 2004

N2 - A new nickel(II)-dicyanamide compound, [Ni(dca)2(en)] n (1) (dca=dicyanamide anion, [N(CN)2]-); en=ethylene diamine), has been synthesized and its structure has been determined by single crystal X-ray diffraction analysis. The crystal is monoclinic, space group P21/n with unit cell dimensions: a=0.6943(1) nm, b=1.041 5(2) nm, c= 1.4132(2) nm, and β=90.381°, Z=4, V=1.011 10(3) nm3. In this compound, the adjacent nickel atoms are connected by dca all in μ1,5-bridging mode to form ladder-like units, which are linked with double dca bridges to generate a regular infinite stair-like structure. Temperature-dependent magnetic susceptibility was also characterized for this compound.

AB - A new nickel(II)-dicyanamide compound, [Ni(dca)2(en)] n (1) (dca=dicyanamide anion, [N(CN)2]-); en=ethylene diamine), has been synthesized and its structure has been determined by single crystal X-ray diffraction analysis. The crystal is monoclinic, space group P21/n with unit cell dimensions: a=0.6943(1) nm, b=1.041 5(2) nm, c= 1.4132(2) nm, and β=90.381°, Z=4, V=1.011 10(3) nm3. In this compound, the adjacent nickel atoms are connected by dca all in μ1,5-bridging mode to form ladder-like units, which are linked with double dca bridges to generate a regular infinite stair-like structure. Temperature-dependent magnetic susceptibility was also characterized for this compound.

KW - Coordination polymer

KW - Magnetism

KW - Nickel compound

KW - Stair-like structure

UR - https://www.scopus.com/pages/publications/33751582080

M3 - Article

AN - SCOPUS:33751582080

SN - 1001-4861

VL - 20

SP - 1245

EP - 1248

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 10

ER -

Synthesis, structure and magnetic property of a two-dimensional stair-like framework: [Ni(μ1,5-dca)2(en)]n

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Synthesis, structure and magnetic property of a two-dimensional stair-like framework: [Ni(μ_1,5-dca)₂(en)]_n