Synthesis of MoS₂ and MoO₂ for their applications in H₂ generation and lithium ion batteries: A review

Scientists increasingly witness the applications of MoS₂ and MoO₂ in the field of energy conversion and energy storage. On the one hand, MoS₂ and MoO₂ have been widely utilized as promising catalysts for electrocatalytic or photocatalytic hydrogen evolution in aqueous solution. On the other hand, MoS₂ and MoO₂ have also been verified as efficient electrode material for lithium ion batteries. In this review, the synthesis, structure and properties of MoS₂ and MoO₂ are briefly summarized according to their applications for H₂ generation and lithium ion batteries. Firstly, we overview the recent advancements in the morphology control of MoS₂ and MoO ₂ and their applications as electrocatalysts for hydrogen evolution reactions. Secondly, we focus on the photo-induced water splitting for H ₂ generation, in which MoS₂ acts as an important co-catalyst when combined with other semiconductor catalysts. The newly reported research results of the significant functions of MoS₂ nanocomposites in photo-induced water splitting are presented. Thirdly, we introduce the advantages of MoS₂ and MoO₂ for their enhanced cyclic performance and high capacity as electrode materials of lithium ion batteries. Recent key achievements in MoS₂- and MoO₂-based lithium ion batteries are highlighted. Finally, we discuss the future scope and the important challenges emerging from these fascinating materials.