Synthesis of a pentalene centered polycyclic fused system

Yuliang Li; Xiaodong Yin; Yongjun Li; Yulan Zhu; Yuhe Kan; Daoben Zhu

doi:10.1021/ol200213h

Synthesis of a pentalene centered polycyclic fused system

Yuliang Li^*
, Xiaodong Yin
, Yongjun Li^*
, Yulan Zhu
, Yuhe Kan
, Daoben Zhu

^*此作品的通讯作者

CAS - Institute of Chemistry
University of Chinese Academy of Sciences
Huaiyin Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

44 引用（Scopus）

摘要

A novel pentalene-centered polycyclic 24π-electron system, IB1, was synthesized via a Pd-catalyzed homocoupling reaction. The geometry structure was studied by X-ray diffraction and theoretical method. The HOMO level of IB1 was studied by electrochemical experiment and DFT methods. The IB1 molecule shows a strong electro-donating property and can form a charge transfer complex with electro-acceptor TCNQ, indicating fascinating potential in the field of organic electronics.

源语言	英语
页（从-至）	1520-1523
页数	4
期刊	Organic Letters
卷	13
期	6
DOI	https://doi.org/10.1021/ol200213h
出版状态	已出版 - 18 3月 2011
已对外发布	是

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title = "Synthesis of a pentalene centered polycyclic fused system",

abstract = "A novel pentalene-centered polycyclic 24π-electron system, IB1, was synthesized via a Pd-catalyzed homocoupling reaction. The geometry structure was studied by X-ray diffraction and theoretical method. The HOMO level of IB1 was studied by electrochemical experiment and DFT methods. The IB1 molecule shows a strong electro-donating property and can form a charge transfer complex with electro-acceptor TCNQ, indicating fascinating potential in the field of organic electronics.",

author = "Yuliang Li and Xiaodong Yin and Yongjun Li and Yulan Zhu and Yuhe Kan and Daoben Zhu",

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AU - Li, Yuliang

AU - Yin, Xiaodong

AU - Li, Yongjun

AU - Zhu, Yulan

AU - Kan, Yuhe

AU - Zhu, Daoben

PY - 2011/3/18

Y1 - 2011/3/18

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AB - A novel pentalene-centered polycyclic 24π-electron system, IB1, was synthesized via a Pd-catalyzed homocoupling reaction. The geometry structure was studied by X-ray diffraction and theoretical method. The HOMO level of IB1 was studied by electrochemical experiment and DFT methods. The IB1 molecule shows a strong electro-donating property and can form a charge transfer complex with electro-acceptor TCNQ, indicating fascinating potential in the field of organic electronics.

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DO - 10.1021/ol200213h

M3 - Article

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Synthesis of a pentalene centered polycyclic fused system

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