Synthesis of 3d-3d heterometallic 4-amino-1,2,4-triazole complex with the structure depending on the reaction time

H. Y. Zhang; H. Li; G. Liu; T. T. Liu; F. Yue; J. D. Wang

doi:10.1134/S1070328411060121

Synthesis of 3d-3d heterometallic 4-amino-1,2,4-triazole complex with the structure depending on the reaction time

H. Y. Zhang
, H. Li
, G. Liu
, T. T. Liu
, F. Yue^*
, J. D. Wang

^*此作品的通讯作者

Xinjiang University

科研成果: 期刊稿件 › 文章 › 同行评审

1 引用（Scopus）

摘要

One-pot reaction containing Zn(NO₃)₂, Cd(NO ₃)₂, NH₄SCN, and 4-amino-1,2,4-triazole (Atrz) was proceeded by refluxing for different periods and gave different products. When the mixture was refluxed for 1 h, the product was a 1D chain polymer [Cd(Atrz)₂(SCN)₂] _n . However, when the refluxing time was increased to 3 h, a novel 3D 3d-3d heterometallic framework complex [Cd_2.84Zn_2.16(Atrz)₆(SCN)₁₀] • 4H₂O (I) with 66 topology was obtained. The photoluminescence property of I in the solid state was discussed..

源语言	英语
页（从-至）	411-416
页数	6
期刊	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
卷	37
期	6
DOI	https://doi.org/10.1134/S1070328411060121
出版状态	已出版 - 6月 2011
已对外发布	是

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@article{02129c9a43074eaaa6e2809c6eba9911,

title = "Synthesis of 3d-3d heterometallic 4-amino-1,2,4-triazole complex with the structure depending on the reaction time",

abstract = "One-pot reaction containing Zn(NO3)2, Cd(NO 3)2, NH4SCN, and 4-amino-1,2,4-triazole (Atrz) was proceeded by refluxing for different periods and gave different products. When the mixture was refluxed for 1 h, the product was a 1D chain polymer [Cd(Atrz)2(SCN)2] n . However, when the refluxing time was increased to 3 h, a novel 3D 3d-3d heterometallic framework complex [Cd2.84Zn2.16(Atrz)6(SCN)10] • 4H2O (I) with 66 topology was obtained. The photoluminescence property of I in the solid state was discussed..",

author = "Zhang, \{H. Y.\} and H. Li and G. Liu and Liu, \{T. T.\} and F. Yue and Wang, \{J. D.\}",

year = "2011",

month = jun,

doi = "10.1134/S1070328411060121",

language = "English",

volume = "37",

pages = "411--416",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

issn = "1070-3284",

publisher = "Pleiades Publishing",

number = "6",

}

TY - JOUR

T1 - Synthesis of 3d-3d heterometallic 4-amino-1,2,4-triazole complex with the structure depending on the reaction time

AU - Zhang, H. Y.

AU - Li, H.

AU - Liu, G.

AU - Liu, T. T.

AU - Yue, F.

AU - Wang, J. D.

PY - 2011/6

Y1 - 2011/6

N2 - One-pot reaction containing Zn(NO3)2, Cd(NO 3)2, NH4SCN, and 4-amino-1,2,4-triazole (Atrz) was proceeded by refluxing for different periods and gave different products. When the mixture was refluxed for 1 h, the product was a 1D chain polymer [Cd(Atrz)2(SCN)2] n . However, when the refluxing time was increased to 3 h, a novel 3D 3d-3d heterometallic framework complex [Cd2.84Zn2.16(Atrz)6(SCN)10] • 4H2O (I) with 66 topology was obtained. The photoluminescence property of I in the solid state was discussed..

AB - One-pot reaction containing Zn(NO3)2, Cd(NO 3)2, NH4SCN, and 4-amino-1,2,4-triazole (Atrz) was proceeded by refluxing for different periods and gave different products. When the mixture was refluxed for 1 h, the product was a 1D chain polymer [Cd(Atrz)2(SCN)2] n . However, when the refluxing time was increased to 3 h, a novel 3D 3d-3d heterometallic framework complex [Cd2.84Zn2.16(Atrz)6(SCN)10] • 4H2O (I) with 66 topology was obtained. The photoluminescence property of I in the solid state was discussed..

UR - https://www.scopus.com/pages/publications/79960069334

U2 - 10.1134/S1070328411060121

DO - 10.1134/S1070328411060121

M3 - Article

AN - SCOPUS:79960069334

SN - 1070-3284

VL - 37

SP - 411

EP - 416

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

IS - 6

ER -

Synthesis of 3d-3d heterometallic 4-amino-1,2,4-triazole complex with the structure depending on the reaction time

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