Synthesis of 3d-3d heterometallic 4-amino-1,2,4-triazole complex with the structure depending on the reaction time

H. Y. Zhang; H. Li; G. Liu; T. T. Liu; F. Yue; J. D. Wang

doi:10.1134/S1070328411110133

Synthesis of 3d-3d heterometallic 4-amino-1,2,4-triazole complex with the structure depending on the reaction time

H. Y. Zhang
, H. Li
, G. Liu
, T. T. Liu
, F. Yue^*
, J. D. Wang

^*此作品的通讯作者

Xinjiang University

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

One-pot reaction containing Zn(NO ₃) ₂, Cd(NO ₃) ₂, NH ₄SCN, and 4-amino-1,2,4-triazole (Atrz) proceeded by refluxing for different periods and gave different products. When the mixture was refluxed for 1 h, the product was a 1D chain polymer [Cd(Atrz) ₂(SCN) ₂] _nHowever, when the refluxing time was increased to 3 h, a novel 3D 3d-3d heterometallic framework complex [Cd _2.84Zn _2.16(Atrz) ₆(SCN) ₁₀] • 4H ₂O (I) with 6 ⁶ topology was obtained. The fluorescent property of I in the solid state was discussed.

源语言	英语
页（从-至）	839-844
页数	6
期刊	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
卷	37
期	11
DOI	https://doi.org/10.1134/S1070328411110133
出版状态	已出版 - 11月 2011
已对外发布	是

访问文件

10.1134/S1070328411110133

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{60acd098b8074dfb9e52a86fecd938f8,

title = "Synthesis of 3d-3d heterometallic 4-amino-1,2,4-triazole complex with the structure depending on the reaction time",

abstract = "One-pot reaction containing Zn(NO 3) 2, Cd(NO 3) 2, NH 4SCN, and 4-amino-1,2,4-triazole (Atrz) proceeded by refluxing for different periods and gave different products. When the mixture was refluxed for 1 h, the product was a 1D chain polymer [Cd(Atrz) 2(SCN) 2] nHowever, when the refluxing time was increased to 3 h, a novel 3D 3d-3d heterometallic framework complex [Cd 2.84Zn 2.16(Atrz) 6(SCN) 10] • 4H 2O (I) with 6 6 topology was obtained. The fluorescent property of I in the solid state was discussed.",

author = "Zhang, \{H. Y.\} and H. Li and G. Liu and Liu, \{T. T.\} and F. Yue and Wang, \{J. D.\}",

year = "2011",

month = nov,

doi = "10.1134/S1070328411110133",

language = "English",

volume = "37",

pages = "839--844",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

issn = "1070-3284",

publisher = "Pleiades Publishing",

number = "11",

}

TY - JOUR

T1 - Synthesis of 3d-3d heterometallic 4-amino-1,2,4-triazole complex with the structure depending on the reaction time

AU - Zhang, H. Y.

AU - Li, H.

AU - Liu, G.

AU - Liu, T. T.

AU - Yue, F.

AU - Wang, J. D.

PY - 2011/11

Y1 - 2011/11

N2 - One-pot reaction containing Zn(NO 3) 2, Cd(NO 3) 2, NH 4SCN, and 4-amino-1,2,4-triazole (Atrz) proceeded by refluxing for different periods and gave different products. When the mixture was refluxed for 1 h, the product was a 1D chain polymer [Cd(Atrz) 2(SCN) 2] nHowever, when the refluxing time was increased to 3 h, a novel 3D 3d-3d heterometallic framework complex [Cd 2.84Zn 2.16(Atrz) 6(SCN) 10] • 4H 2O (I) with 6 6 topology was obtained. The fluorescent property of I in the solid state was discussed.

AB - One-pot reaction containing Zn(NO 3) 2, Cd(NO 3) 2, NH 4SCN, and 4-amino-1,2,4-triazole (Atrz) proceeded by refluxing for different periods and gave different products. When the mixture was refluxed for 1 h, the product was a 1D chain polymer [Cd(Atrz) 2(SCN) 2] nHowever, when the refluxing time was increased to 3 h, a novel 3D 3d-3d heterometallic framework complex [Cd 2.84Zn 2.16(Atrz) 6(SCN) 10] • 4H 2O (I) with 6 6 topology was obtained. The fluorescent property of I in the solid state was discussed.

UR - https://www.scopus.com/pages/publications/83455259386

U2 - 10.1134/S1070328411110133

DO - 10.1134/S1070328411110133

M3 - Article

AN - SCOPUS:83455259386

SN - 1070-3284

VL - 37

SP - 839

EP - 844

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

IS - 11

ER -

Synthesis of 3d-3d heterometallic 4-amino-1,2,4-triazole complex with the structure depending on the reaction time

摘要

访问文件

其它文件与链接

指纹

引用此